hydroxy(methyl)propenoic acid ethyl ester | 83742-49-8

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: hydroxy(methyl)propenoic acid ethyl ester
• 英文别名: hydroxy ethyl crotonate；ethyl (Z)-2-hydroxybut-2-enoate
• CAS: 83742-49-8
• 化学式: C₆H₁₀O₃
• 分子量: 130.144
• InChiKey: SLWKIJNJCXVBNR-HYXAFXHYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.2
• 重原子数：
  9
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  46.5
• 氢给体数：
  1
• 氢受体数：
  3

文献信息

• Purified styrene-maleic anhydride polymer binder
  申请人：Shooshtari Kiarash Alavi

  公开号：US20090182108A1

  公开（公告）日：2009-07-16

  An aqueous binding composition is provided comprised of a polyanhydride based polymer, which polyanhydride based polymer has been purified through the use of an azeotrope. The resulting binder is effective, particularly for binding glass fibers, yet substantially odor free. A fibrous material is provided that is coated with a water-resistant cured binder formed in accordance with the process of the present invention wherein adjoining fibers are bound at cross-over points. Such bound fibrous material is free of a phenol-formaldehyde resin and substantially free of odor. It has been found that by removing purities such as cumene and acetophenone from a polyanhydride binder, e.g., a styrene maleic anhydride based polymer based binder, an effective binder for glass fiber is obtained while also avoiding an odor problem.

  提供一种水基粘结组合物，由基于聚酸酐的聚合物组成，该聚酸酐聚合物经过以共沸剂为基础的纯化。由此形成的粘合剂非常有效，特别适用于玻璃纤维的粘结，且基本无异味。提供了一种被水性耐久粘结剂涂覆的纤维材料，该粘结剂是根据本发明的工艺形成的，相邻的纤维在交叉点处被粘结。这样的粘结纤维材料不含酚醛树脂，且基本无异味。发现通过去除聚酸酐粘合剂中的杂质，例如甲苯和乙酰苯，例如基于苯乙烯马来酸酐的聚合物基粘合剂，可以获得一种有效的玻璃纤维粘合剂，同时避免异味问题。
• Method for repairing glass fiber reinforced plastic parts
  申请人：GENCORP INC.

  公开号：EP0092894A2

  公开（公告）日：1983-11-02

  Surface defects in a cured, molded thermoset fiberglass reinforced (FRP) part can be repaired by filling the defect or void with an excess of a thermosetting conductive repair material, applying pressure and heat sufficient to cure said material without substantial shrinkage of said material, removing the pressure, cooling and finishing said parts to the original surface contour. The repair material includes a polyurethane/acrylate, an epoxy/acrylate or an unsaturated polyester oligomer, three ethylenically unsaturated components copolymerizable with the oligomer, one of which is an acrylate and another of which has a -CO- group and a -NHz, -NH- and/or -OH group, release agents, an initiator, an accelerator, a low profile additive and filler materials, one of which is conductive.

  固化成型的热固性玻璃纤维增强（FRP）部件的表面缺陷可通过以下方法进行修复：用过量的热固性导电修复材料填充缺陷或空隙，施加足够的压力和热量使所述材料固化，而不会使所述材料产生大量收缩，移除压力，冷却并将所述部件修整至原始表面轮廓。修复材料包括聚氨酯/丙烯酸酯、环氧树脂/丙烯酸酯或不饱和聚酯低聚物、三种可与低聚物共聚的乙烯基不饱和组分（其中一种是丙烯酸酯，另一种具有-CO-基团和-NHz、-NH-和/或-OH基团）、脱模剂、引发剂、促进剂、低剖面添加剂和填充材料（其中一种为导电材料）。
• Thermosetting in-mold coating compositions
  申请人：GENCORP INC.

  公开号：EP0396837A2

  公开（公告）日：1990-11-14

  A fiber glass reinforced plastic can be in-mold coated utilizing a free radical peroxide initiated thermosetting composition of at least one polymerizable epoxy based oligomer having at least two acrylate groups, at least one copolymerizable ethylenically unsaturated monomer, at least one copolymerizable monoethylenically unsaturated compound having a -CO- group and a -NH₂, -NH- and/or -OH group, and other conventional components such as at least one zinc salt of a fatty acid, at least one accelerator, at least one filler, and the like. The thermosetting compositions of the present invention uti­lize a very low or nil amount of an adhesion agent such as a polyvinyl acetate and unexpectedly achieves better flow and good coverage at reduced coating weights.

  玻璃纤维增强塑料可以利用自由基过氧化物引发的热固性组合物进行模内涂覆，该组合物包括至少一种具有至少两个丙烯酸酯基团的可聚合环氧基低聚物、至少一种可共聚的乙烯基不饱和单体、至少一种具有-CO-基团和-NH₂、-NH和/或-OH基团的可共聚的单乙烯基不饱和化合物，以及其他常规成分，例如至少一种具有-CO-基团和-NH₂、-NH-和/或-OH基团的可共聚单乙烯基不饱和化合物，以及其他常规成分，如至少一种脂肪酸锌盐、至少一种促进剂、至少一种填料等。本发明的热固性组合物使用极少量或零用量的粘合剂，如聚醋酸乙烯酯，在减少涂层重量的情况下，意外地获得了更好的流动性和良好的覆盖性。
• In mold coating compositions
  申请人：GENCORP INC.

  公开号：EP0461320A1

  公开（公告）日：1991-12-18

  An FRP molding can be in-mold coated using a free radical peroxide initiated thermosetting composition of at least one polymerizable epoxy based oligomer having at least two acrylate groups, at least one copolymerizable ethylenically unsaturated monomer, at least one copolymerizable monoethylenically unsaturated compound having a -CO- group and a -NH₂, -NH- and/or -OH group, polyvinyl acetate, at least one zinc salt of a fatty acid, at least one calcium salt of a fatty acid, at least one accelerator for a peroxide initiator, conductive carbon black, a filler such as talc and containing as an additive a soluble ionic organic salt, which is an ammonium arylsulphonate, e.g. tetraethylammonium p-toluenesulphonate.

  -或 -OH 基团的可共聚单亚乙基不饱和化合物、聚醋酸乙烯酯、至少一种脂肪酸锌盐、 至少一种脂肪酸钙盐、至少一种过氧化物引发剂促进剂、导电炭黑、填料（如滑石粉） 以及作为添加剂的可溶性离子有机盐（如芳基磺酸铵）。例如对甲苯磺酸四乙基铵。
• In-mould coating compositions and use thereof
  申请人：GENCORP INC.

  公开号：EP0504528A1

  公开（公告）日：1992-09-23

  The cure rate or time of an in-mold coating composition is greatly enhanced by the use of a minor component by weight of a catalyst or initiator in the in-mold composition comprising essentially t-butyl peroxyisobutyrate.

  在模内涂料组合物中使用少量催化剂或引发剂（按重量计），可大大提高模内涂料组合物的固化率或固化时间，这些催化剂或引发剂主要包括过氧化异丁酸叔丁酯。