trifluoromethanesulfonic acid 3,4-dicyanophenyl ester | 1007894-22-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: trifluoromethanesulfonic acid 3,4-dicyanophenyl ester
• 英文别名: (3,4-Dicyanophenyl) trifluoromethanesulfonate
• CAS: 1007894-22-5
• 化学式: C₉H₃F₃N₂O₃S
• 分子量: 276.196
• InChiKey: IAOBZMMIGUDWLF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  18
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  99.3
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  trifluoromethanesulfonic acid 3,4-dicyanophenyl ester 、 4-叔丁基苯酚 、 三氯化硼 以 对二甲苯 、 甲苯 为溶剂， 以35 %的产率得到
  参考文献：
  名称：

  Borylated Subphthalocyanines: Versatile Precursors for the Preparation of Functional Bowl‐Shaped Aromatics

  摘要：

  摘要卟啉的外围硼酸化已成为制备先进功能材料的关键步骤。本研究报道了硼化亚酞菁的合成、电子特性和反应活性。这些化合物通过 Suzuki-Miyaura 硼酰化法制备，收率极高，易于纯化，具有极高的稳定性，是通过交叉偶联反应对 SubPcs 进行后功能化的有力起始材料。值得注意的是，这种新方法比已描述过的方法更有效，并能制备出奇特的系统，如通过 C-C 键连接的 SubPc 二聚物，这些系统迄今为止还无法获得，但在光电设备方面具有广阔的应用前景。

  DOI：

  10.1002/chem.202301782

文献信息

• Aryl triflate compound, radiologically acid producing agent, radiologically acid producing agent system, and radiosensitive composition
  申请人：HITACHI CHEMICAL CO., LTD.

  公开号：EP0537879A1

  公开（公告）日：1993-04-21

  Aryl triflate compounds can generate a strong acid when exposed to irradiation of radiation and can be used as an acid generator in a radiologically-acid-producing agent system and a radiosensitive composition.

  三酸芳基酯化合物在受到辐射辐照时可生成强酸，可用作辐射产酸剂系统和辐射敏感组合物中的产酸剂。
• MATERIAL FOR ORGANIC ELECTROLUMINESCENT ELEMENT AND ORGANIC ELECTROLUMINESCENT ELEMENT
  申请人：Idemitsu Kosan Co., Ltd

  公开号：EP2790239A1

  公开（公告）日：2014-10-15

  A material for organic electroluminescence device having a specific central skeleton to which a cyano-substituted aromatic hydrocarbon group or a cyano-substituted heterocyclic group is bonded at its specific position is described. Further described is an organic electroluminescence device including an organic thin film layer between an anode and a cathode. The organic thin film layer include an light emitting layer and at least one layer of the organic thin film layer contains the material for organic electroluminescence device. The material for organic electroluminescence device realizes an organic electroluminescence device with good emission efficiency.

  本文描述了一种用于有机电致发光装置的材料，该材料具有特定的中心骨架，在其特定位置上键合有氰基取代的芳香烃基团或氰基取代的杂环基团。进一步描述了一种有机电致发光器件，包括阳极和阴极之间的有机薄膜层。有机薄膜层包括发光层，有机薄膜层的至少一层包含有机电致发光器件材料。有机电致发光器件材料实现了具有良好发射效率的有机电致发光器件。
• MATERIAL FOR ORGANIC ELECTROLUMINESCENCE DEVICE AND ORGANIC ELECTROLUMINESCENCE DEVICE
  申请人：MIZUKI Yumiko

  公开号：US20140001446A1

  公开（公告）日：2014-01-02

  A material for organic electroluminescence device having a specific central skeleton to which a cyano-substituted aromatic hydrocarbon group or a cyano-substituted heterocyclic group is bonded at its specific position is described. Further described is an organic electroluminescence device including an organic thin film layer between an anode and a cathode. The organic thin film layer include an light emitting layer and at least one layer of the organic thin film layer contains the material for organic electroluminescence device. The material for organic electroluminescence device realizes an organic electroluminescence device with good emission efficiency.
• US5198402A
  申请人：——

  公开号：US5198402A

  公开（公告）日：1993-03-30
• US5302725A
  申请人：——

  公开号：US5302725A

  公开（公告）日：1994-04-12