| 207676-27-5

• CAS: 207676-27-5
• 化学式: C₄₄H₇₄Ga₂N₂O₂
• 分子量: 802.53
• InChiKey: KUVJEKVKUNATPB-VXSSHDPHSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  三乙基镓 、 N,N'-bis(3,5-di-t-butylsalicylidene)-1,6-diaminohexane 以 甲苯 为溶剂， 以74%的产率得到
  参考文献：
  名称：

  Bimetallic mixed-metal complexes of the ligands

  摘要：

  The Salen(Bu-t) ligands, Salen(Bu-t), (N,N'-ethylenebis(3,5-di-tert-butylsalicylideneimine) and Salpen(Bu-t), (N,N'-propylenebis(3,5-di-tert-butylsalicylideneimine) can be combined with GaEt3 to prepare the 'open' monometallic compounds, Salen(Bu-t)H(GaEt2) (1) and Salpen(Bu-t)(GaEt2) (2). These, in turn, can be converted to the bimetallic derivatives, Salen(t)Bu(GaEt2)(2) (3) and Salpen(Bu-t)(GaEt2)(2) (4) by addition of GaEt3. Alternatively, 3 and 4 can be made by the addition of two moles of GaEt3 to the appropriate ligand. This was the method used to prepare Salben(Bu-t)(GaEt2)(2) (5) (Salben(Bu-t) = N,N'-butylenebis(3,5-di-tert-butylsalicylideneimine) and Salhen(Bu-t)(GaEt2)(0) (6) [Salhen(Bu-t) = N,N'-hexylenebis(3,5-di-tert-butylsalicylideneimine]. Compounds 1 and 2 can be utilized to form the unique mixed-metal derivatives L(GaEt2) (MR2) (where L = Salen(Bu-t), M : R = Al, Me (7); Al, Et (9); and L = Salpen(Bu-t), M: R = Al, Me (8); Al, Et (10). At ambient temperatures in non-polar solvents, 7-12 do not undergo exchange of either the alkyl or MR2 groups. All of the compounds were characterized by Mp, analyses, H-1 NMR, IR and, in the case of 1 and 3-6, by X-ray crystallography. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(97)00293-3