4-tetradecyloxy-N-dodecyl-2-hydroxybenzaldimine | 271577-89-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 4-tetradecyloxy-N-dodecyl-2-hydroxybenzaldimine
• 英文别名: 2-(Dodecyliminomethyl)-5-tetradecoxyphenol
• CAS: 271577-89-0
• 化学式: C₃₃H₅₉NO₂
• 分子量: 501.837
• InChiKey: YJVDLZOPAWMTJX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13.4
• 重原子数：
  36
• 可旋转键数：
  26
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.79
• 拓扑面积：
  41.8
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  neodymium(III) nitrate hexahydrate 、 4-tetradecyloxy-N-dodecyl-2-hydroxybenzaldimine 以 乙醇 为溶剂， 以71%的产率得到(4-tetradecyloxy-N-dodecyl-2-hydroxybenzaldimine)3(NO3)3 neodymium(III) complex
  参考文献：
  名称：

  Mesomorphic lanthanide complexes with azomethine ligands

  摘要：

  The synthesis and mesophase behaviour of lanthanide complexes with azomethine (Schiff base) ligands is described. The ligands are 4-tetradecyloxy-N-alkyl-2-hydroxybenzaldimines, where the alkyl chain on the imine nitrogen is C8H17, C12H25 or C18K37. The stoichiometry of the complexes formed by the reaction of the hydrated nitrates of the lanthanides with the azomethines is [Ln(LH)(3)(NO3)(3)]. All these coordination compounds exhibit liquid-crystalline properties. A viscous smectic A (SmA) mesophase is formed. The mesophase of these metallomesogens can be supercooled to a glassy state. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0925-8388(00)00623-x