N-benzyl-3-(3-methylimidazol-3-ium-1-yl)propan-1-amine;hexafluorophosphate | 820220-13-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-benzyl-3-(3-methylimidazol-3-ium-1-yl)propan-1-amine;hexafluorophosphate
• CAS: 820220-13-1
• 化学式: C₁₄H₂₀N₃*F₆P
• 分子量: 375.297
• InChiKey: XYDWRJVEGDABMZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  二硫化碳 、 ammonium hexafluorophosphate 、 N-benzyl-3-(3-methylimidazol-3-ium-1-yl)propan-1-amine;hexafluorophosphate 、 zinc diacetate 在 三乙胺 作用下， 以 乙腈 为溶剂， 以78%的产率得到
  参考文献：
  名称：

  Acyclic and macrocyclic transition metal dithiocarbamate complexes containing imidazolium moieties for anion binding

  摘要：

  The synthesis of acyclic and macrocyclic transition metal dithiocarbamate complexes containing positively charged imidazolium moieties is reported. The assemblies have been characterised by a range of spectroscopic techniques and the ability of these compounds to bind various anions was also examined. UV-Vis spectroscopic binding studies revealed H2PO4- is complexed selectively in preference to F- and Cl- for the acyclic transition metal dithiocarbamate complexes containing the N-methylimidazolium moiety. Cyclic voltammetric studies demonstrated that the copper(II) dithiocarbamate imidazolium systems can electrochemically sense the binding of Cl- and H2PO4-. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2004.06.020