1,1,1-trifluoroundecane | 62126-97-0

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氟化物
• 英文名称: 1,1,1-trifluoroundecane
• 英文别名: 1,1,1-Trifluorundecan
• CAS: 62126-97-0
• 化学式: C₁₁H₂₁F₃
• 分子量: 210.283
• InChiKey: BLBMAMWJQCCOPZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.4
• 重原子数：
  14
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  2-decyl-1,3-dithiane 在 正丁基锂 、 三氟化溴 作用下， 以 四氢呋喃 、 正己烷 、 一氟三氯甲烷 为溶剂， 反应 2.5h， 生成 1,1,1-trifluoroundecane
  参考文献：
  名称：

  Constructing the CF3 group; unique trifluorodecarboxylation induced by BrF3

  摘要：

  A variety of 2-alkyl-1,3-dithiane-2-carboxylic acids was prepared from the appropriate alkyl halides, 1,3-dithiane and CO2. These acids were reacted with BrF3 to form the trifluoromethylalkyl derivatives via a combination of ionic and radical trifluorodecarboxylation in about 50-60% yield. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2004.11.063

文献信息

• Liquid crystal compounds and compositions
  申请人：SANYO CHEMICAL INDUSTRIES LTD.

  公开号：EP0517498A1

  公开（公告）日：1992-12-09

  Liquid crystal naphtalene compounds, represented by the following formula (1) are disclosed.         R-Z-A-NAP-Z′-R′   (1) In the formula (1), R is an alkyl group containing 1 to 18 carbon atoms; R′ is an alkyl group containing 1 to 21 carbon atoms; NAP represents 2,6-naphthylene group; A, Z and Z′ are as follows: 1) A is Pyr> and (a) Z is - or # and Z′ is O, or (b) Z is - and Z′ is COO; 2) if A is Pym>, (a) Z is - and Z′ is O, or (b) Z is O and Z′ is -, O or #; 3) A is FPhF and (a) Z is - or O and Z′ is -, O or COO, (b) Z is OCO and Z′ is - or O, or (c) Z is # and Z′ is O; 4) A is PhF and (a) Z is - or # and Z′ is O, (b) Z is O and Z′ is -, or (c) Z is - and Z′ is COO; 5) A is FPh and (a) Z is O and Z′ is-, (b) Z is -, O, # or OCO and Z′ is O, or (c) Z is O and Z′ is COO; 6) A is

  液晶萘化合物的化学式如下所示：R-Z-A-NAP-Z′-R′。在这个化学式中，R是含有1到18个碳原子的烷基基团；R′是含有1到21个碳原子的烷基基团；NAP代表2,6-萘基团；A、Z和Z′的具体定义如下： 1）如果A是Pyr，(a) Z是-或#，Z′是O；或者(b) Z是-，Z′是COO； 2）如果A是Pym，(a) Z是-，Z′是O；或者(b) Z是O，Z′是-、O或#； 3）如果A是FPhF，(a) Z是-或O，Z′是-、O或COO；(b) Z是OCO，Z′是-或O；或者(c) Z是#，Z′是O； 4）如果A是PhF，(a) Z是-或#，Z′是O；(b) Z是O，Z′是-；或者(c) Z是-，Z′是COO； 5）如果A是FPh，(a) Z是O，Z′是-；(b) Z是-、O、#或OCO，Z′是O；或者(c) Z是O，Z′是COO； 6）如果A是
• From Alkyl Halides to Alkyltrifluoromethyls Using Bromine Trifluoride
  作者：Aviv Hagooly、Iris Ben-David、Shlomo Rozen

  DOI：10.1021/jo026128b

  日期：2002.11.1

  right conditions, bromine trifluoride can be a useful tool for generating new types of reactions and compounds. Thus, tris(methylthio)alkyl derivatives, easily prepared from the corresponding alkyl bromides, were converted to the corresponding RCHBrCF2SMe or RCHBrCF3 compounds. The bromine atom, however, could be easily reduced forming eventually R'CF2SMe or R'CF3. If desired, the bromine atom can serve

  在适当的条件下，三氟化溴可能是产生新型反应和化合物的有用工具。因此，容易从相应的烷基溴制备的三（甲硫基）烷基衍生物被转化为相应的RCHBrCF2SMe或RCHBrCF3化合物。但是，溴原子很容易还原，最终形成R'CF2SMe或R'CF3。如果需要，溴原子可以用作构建末端二氟烯烃的入口。
• METHOD OF MANUFACTURING FLUORINE-CONTAINING COMPOUND
  申请人：AGC Inc.

  公开号：US20220204444A1

  公开（公告）日：2022-06-30

  The present invention is directed to providing a method of manufacturing a fluorine-containing compound according to which a fluorine-containing compound is manufactured under a relatively moderate reaction condition by use of a readily available compound. A method of manufacturing a fluorine-containing compound includes reacting a compound having a partial structure expressed by a formula (a) below with a Grignard reagent in the presence of a transition metal compound, —CF 2 —CH 2 —L  (a) wherein L is a sulfonate group.

  本发明旨在提供一种制造含氟化合物的方法，该方法利用易得到的化合物在相对温和的反应条件下制造含氟化合物。一种制造含氟化合物的方法包括在过渡金属化合物的存在下，将一个部分结构由下式（a）表示的化合物与格氏试剂反应，其中L是磺酸盐基：—CF2—CH2—L  (a)。
• Liquid crystal compounds and optically active compounds
  申请人：SANYO CHEMICAL INDUSTRIES LTD.

  公开号：EP0409634A2

  公开（公告）日：1991-01-23

  A compound usefull for liquid crystal component which is represented by the following formulas (1), (2), (3), or (4) ; wherein R1 ,R2 ,R3 and R4 are C1 -1 8 alkyl groups; X1 and X2 is -, 0, S, -C≡C- or divarent groups such as COO, OCO, CH2 O or OCH2 ; Y1 is -CH2 CH2 - or -C ≡ C- ; A1 is 1,4-phenylene-group, A2 , A3, A5 are such as 1,4-phenylene-group; A4 is

  由以下公式（1）、（2）、（3）或（4）表示的可用于液晶成分的化合物； 其中 R1、R2、R3 和 R4 为 C1 -1 8 烷基；X1 和 X2 为-、0、S、-C≡C- 或亲和基，如 COO、OCO、CH2 O 或 OCH2；Y1 为-CH2 CH2 - 或-C≡C-；A1 为 1,4-亚苯基、 A2、A3、A5 为 1,4-亚苯基；A4 为 1,4-亚苯基；A6 为 1,4-亚苯基；A7 为 1,4-亚苯基。
• USE OF COMPOSITIONS COMPRISING POLYMERIC INERT BINDERS FOR THE FABRICAITON OF LIGHT-EMITTING DIODE
  申请人：Merck Patent GmbH

  公开号：EP2725632A1

  公开（公告）日：2014-04-30

  The present invention relates to novel compositions comprising light emitting materials and/or charge transport materials and a polymeric binder, to their use as conducting inks for the preparation of organic light emitting diode (OLED) devices, to methods for preparing OLED devices using the novel formulations, and to OLED devices prepared from such methods and formulations.

  本发明涉及由发光材料和/或电荷传输材料以及聚合物粘合剂组成的新型组合物，涉及将其用作制备有机发光二极管（OLED）器件的导电油墨，涉及使用新型配方制备 OLED 器件的方法，还涉及使用此类方法和配方制备的 OLED 器件。