1,3-dibenzyl-2-(phenylazo)imidazolium iodide | 913291-98-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,3-dibenzyl-2-(phenylazo)imidazolium iodide
• 英文别名: [Haai(CH2Ph)2(1+)]I-；[Haai(CH2Ph)2]I
• CAS: 913291-98-2
• 化学式: C₂₃H₂₁N₄*I
• 分子量: 480.351
• InChiKey: QHCXVOLNEAODIV-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  2.29
• 重原子数：
  28.0
• 可旋转键数：
  6.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  33.53
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  silver(I) iodide 、 1,3-dibenzyl-2-(phenylazo)imidazolium iodide 以 甲醇 为溶剂， 生成 [Haai(CH2Ph)2]2[Ag3I5]
  参考文献：
  名称：

  Azoimidazolium iodocuprate(I) and iodoargentate(I)

  摘要：

  1,3-Di-alkyl-2-(arylazo)imidazolium iodide (RaaiR'I-+(2)-) has been used to prepare iodocuprate(I) and iod oargentate(I) complexes. The structural confirmation has been carried out by single crystal X-ray diffraction study in representative cases. Iodo bridged anion, [Cu-2(mu-I)(2)I-2](2-), serves as charge support to dialkylazoimidazolium ion (RaaiR'(+)(2)). Silver(I) compound is a trimeric iodo-bridged [Ag3I5](2-) that forms ID chain while imidazolium ion. RaaiR'(+)(2), is penetrating into the network. Electrostatic interaction between organic cation and inorganic anion and supramolecular interactions viz. hydrogen bonding, D-H-pi, pi-pi interactions contribute to the crystal packing. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2009.07.034
• 作为产物：
  描述：

  1-benzyl-2-(phenylazo)imidazole 、 苄基碘 以 四氢呋喃 为溶剂， 生成 1,3-dibenzyl-2-(phenylazo)imidazolium iodide
  参考文献：
  名称：

  Mallick; Sarker; Saha, Journal of the Indian Chemical Society, 2011, vol. 88, # 12, p. 1817 - 1825

  摘要：

  DOI：

文献信息

• Iodo bridged lead(II) compounds of azoimidazoles: Single crystal X-ray structures of [di-iodo-{1-methyl-2-(p-tolylazo)imidazole}lead(II)]n and {1-methyl-3-benzyl-2-(p-tolylazo)imidazolium}m-{tri-iodoplumbate(II)}m
  作者：K.K. Sarker、A.D. Jana、G. Mostafa、J.-S. Wu、T.-H. Lu、C. Sinha

  DOI：10.1016/j.ica.2006.05.037

  日期：2006.10

  PbI2 forms iodo-bridged neutral polymer upon reaction with 1-alkyl-2-(arylazo)imidazoles (RaaiR'). The reaction of PbI2 and dialkyl imidazolium iodides [RaaiR'R"]I-+(-) has synthesized 1,3-dialkyl-2-(arylazo)imidazolium}(m)-tri-iodoplumbate(II)}(m). The complexes are characterized by different spectroscopic studies. Iodobridged chelated polymer, [Pb(RaaiR')I-2]n, has been established by single crystal X-ray diffraction measurements in one case. Tri-iodoplumbates form iodo bridged anion polymer, which connects [RaaiR'R"](+) by hydrogen bonding and are placed in between the pillars of [Pb(mu-I)(6)](n), motif. (c) 2006 Elsevier B.V. All rights reserved.
• Mallick; Saha; Sarker, Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 2012, vol. 51, # 7, p. 917 - 926
  作者：Mallick、Saha、Sarker、Dattad、Sinha

  DOI：——

  日期：——