pyren-1-yl-hydrazine | 110056-95-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 芘
• 英文名称: pyren-1-yl-hydrazine
• 英文别名: Pyren-1-yl-hydrazin；Pyren-1-ylhydrazine
• CAS: 110056-95-6
• 化学式: C₁₆H₁₂N₂
• 分子量: 232.285
• InChiKey: GPITZQISDXHLBB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  18
• 可旋转键数：
  1
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  38
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N-Boc-L-缬氨酸 、 pyren-1-yl-hydrazine 在 1-羟基苯并三唑 、 盐酸-N-乙基-Nˊ-(3-二甲氨基丙基)碳二亚胺 作用下， 以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  用于靛红与酮的对映选择性羟醛反应的简单伯氨基酰胺有机催化剂

  摘要：

  发现使用新设计的氨基酰胺有机催化剂，各种靛红与酮的对映选择性羟醛反应可提供手性 3-取代 3-羟基-2-羟吲哚，收率良好至极好，立体选择性（高达 99 %，高达 98 % ee，同步/反 = 99:1); 一种催化剂，3i，证明特别成功。所得羟吲哚中的一种，3-羟基-3-(2-氧代环己基)-2-吲哚酮可用作药学上重要化合物的合成中间体，并且就其本身而言，显示出有趣的抗惊厥活性。

  DOI：

  10.1002/ejoc.201600414
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 盐酸 、 tin(ll) chloride 作用下， 生成 pyren-1-yl-hydrazine
  参考文献：
  名称：

  The Preparation of Substituted Hydrazines. IV. Arylhydrazines via Conventional Methods¹

  摘要：

  DOI：

  10.1021/jo01110a004

文献信息

• Titanyl phthalocyanine crystal and production method of the same, and electrophotosensitive material
  申请人：——

  公开号：US20040049027A1

  公开（公告）日：2004-03-11

  The present invention relates to a novel titanyl phthalocyanine crystal which can prepare a coating solution having excellent storage stability because it satisfies both of the following two characteristics (a) and (b), a method of producing the same, an electrophotosensitive material using the above crystal as an electric charge generating material. (a) The crystal has a maximum peak at a Bragg angle 2&thgr;±0.2°=27.2° and has no peak at 7.4° in a CuK&agr; characteristic X-ray diffraction spectrum. (b) The crystal does not have a peak of a change in temperature within a range from 50 to 400° C. except for a peak associated with evaporation of adsorbed water in differential scanning calorimetry.

  本发明涉及一种新型钛酸锂酞菁晶体，该晶体能够制备具有优异储存稳定性的涂层溶液，因为它满足以下两个特征(a)和(b)，以及生产该晶体的方法，以及将上述晶体作为电荷生成材料的电感光材料。(a) 该晶体在铜Kα特征X射线衍射谱中在Bragg角2θ±0.2°=27.2°处具有最大峰，并且在7.4°处没有峰。(b) 该晶体在从50到400°C范围内没有温度变化的峰，除了在差示扫描量热法中与吸附水蒸发相关的峰。
• Electrophotographic photoreceptor
  申请人：Mitsubishi Chemical Corporation

  公开号：EP0568007A1

  公开（公告）日：1993-11-03

  An electrophotographic photoreceptor comprising an electrically conductive substrate and a photosensitive layer formed thereon, wherein said photosensitive layer contains an arylamine compound of the following formula (I): wherein X is a hydrogen atom or a group of the formula (II): Y is a group of the formula (III) or (IV):         -O-A¹-O-   (III)         -A²-O-A³-   (III) wherein A¹ in the formula (III) is a bivalent hydrocarbon residue which may have substituents, and each of A² and A³ in the formula (IV) is an alkylene group which may have substituents, an arylene group which may have substituents, or a group wherein an alkylene group which may have substituents and an arylene group which may have substituents, are bonded, and A² and A³ may be the same or different from each other; each of Ar¹ and Ar² which may be the same or different, is an alkyl group which may have substituents, an aryl group which may have substituents, or a heterocyclic group which may have substituents; each of R¹, R², R³ and R⁴ which may be the same or different, is a hydrogen atom, a halogen atom, an alkyl group which may have substituents, an alkoxy group which may have substituents, or a substituted amino group; each of R⁵, R⁶, R⁷, R⁸, R⁹ and R¹⁰ which may be the same or different, is a hydrogen atom, an alkyl group which may have substituents, an aryl group which may have substituents, or a heterocyclic group which may have substituents, or R⁶ and R⁷, or R⁹ and R¹⁰ are condensed to form a carbon ring group which may have substituents, or a heterocyclic group which may have substituents, provided that with respect to the pair of R⁶ and R⁷ and the pair of R⁹ and R¹⁰, when one of each pair is a hydrogen atom or an alkyl group, the other is an aryl group or a heterocyclic group.

  一种电子照相感光器，包括导电基底和在其上形成的感光层，其中所述感光层含有下式 (I) 的芳基胺化合物： 其中 X 为氢原子或式（II）的基团： Y 是式 (III) 或 (IV) 的基团： -O-A¹-O- (III) -a²-o-a³- (iii) 其中，式（III）中的 A¹ 为可带取代基的二价烃残基，式（IV）中的 A² 和 A³ 分别为可带取代基的亚烷基、可带取代基的亚芳基或可带取代基的亚烷基和可带取代基的亚芳基键合的基团，且 A² 和 A³ 可相同或不同；Ar¹ 和 Ar² 可以相同或不同，各自为可带取代基的烷基、可带取代基的芳基或可带取代基的杂环基；R¹、R²、R³ 和 R⁴ 中的每一个可以相同或不同，是氢原子、卤素原子、可带取代基的烷基、可带取代基的烷氧基或取代的氨基；可相同或不同的 R⁵、R⁶、R⁷、R⁸、R⁹ 和 R¹⁰ 中的每一个是氢原子、可带取代基的烷基、可带取代基的芳基或可带取代基的杂环基，或 R⁶ 和 R⁷、或 R⁹和 R¹⁰ 缩合形成可具有取代基的碳环基团或可具有取代基的杂环基团，但就 R⁶ 和 R⁷ 这一对以及 R⁹ 和 R¹⁰ 这一对而言，当每对中的一个为氢原子或烷基时，另一个为芳基或杂环基团。
• Titanyl phthalocyanine crystal and production method of the same, and electrophotosensitive material and production method of the same
  申请人：KYOCERA MITA CORPORATION

  公开号：EP1093025A2

  公开（公告）日：2001-04-18

  The present invention relates to a titanyl phthalocyanine crystal having excellent storage stability of coating solution, to satisfy that (a) the crystal does not have a peak of a change in temperature except for a peak associated with evaporation of adsorbed water in differential scanning calorimetry or that (b) the crystal recovered after dipping in an organic solvent for 24 hours at least a maximum peak at a Bragg angle 2θ ± 0.2°= 27.2° and has no peak at 26.2° in a CuK α characteristic X-ray diffraction spectrum, and a method of producing the same; and an electrophotosensitive material using the above crystal, and a method of producing the same.

  本发明涉及一种钛酞菁晶体，该晶体具有优异的涂布溶液贮存稳定性，满足以下条件：(a)在差示扫描量热法中，除了与吸附水蒸发有关的峰值外，晶体没有温度变化峰值；或(b)晶体在有机溶剂中浸渍24小时后，在布拉格角2θ±0.2°= 27.2°的最大峰，并且在CuK α特征X射线衍射谱中在26.2°处没有峰，以及生产该晶体的方法；以及使用上述晶体的电致发光材料，以及生产该晶体的方法。
• Titanylphthalocyanin crystal, method for preparing the same, and electrophotographic photoreceptor
  申请人：KYOCERA MITA CORPORATION

  公开号：EP1788037A1

  公开（公告）日：2007-05-23

  According to the present invention, a titanyl phthalocyanin crystal excellent in storage stability in organic solvents, a method for preparing the same and an electrophotographic photoconductor using the same are provided. In the titanyl phthalocyanin crystal, the method for preparing such a titanyl phthalocyanin crystal and the electrophotographic photoconductor using the same, the titanyl phthalocyanin crystal is characterized by having the maximum peak at a Bragg angle 2θ ± 0.2° = 27.2° in a CuKα characteristic X-ray diffraction spectrum and one peak within the range of 270 to 400°C other than a peak accompanied by the vaporization of adsorbed water in a differential scanning calorimetric analysis.

  根据本发明，提供了一种在有机溶剂中存储稳定性极佳的钛酞菁晶体、制备该晶体的方法以及使用该晶体的电子照相光电导体。在该钛酞菁晶体、制备该钛酞菁晶体的方法和使用该晶体的电致发光光电导体中，该钛酞菁晶体的特点是在 CuKα 特征 X 射线衍射谱中具有布拉格角 2θ±0.2°=27.2° 的最大峰值，并且在差示扫描量热分析中，除了伴随吸附水汽化的峰值外，在 270 至 400°C 范围内有一个峰值。
• Oxo-titanylphthalocyanine crystal, method for producing the same, and electrographic photoreceptor
  申请人：KYOCERA MITA CORPORATION

  公开号：EP1884544B1

  公开（公告）日：2011-09-07