4-methoxy-2,6-diacetylpyridine bis(2,4,6-trimethylphenylimine) | 1250445-94-3

• 分子结构分类: 有机化合物
• 英文名称: 4-methoxy-2,6-diacetylpyridine bis(2,4,6-trimethylphenylimine)
• 英文别名: 1-[4-methoxy-6-[C-methyl-N-(2,4,6-trimethylphenyl)carbonimidoyl]pyridin-2-yl]-N-(2,4,6-trimethylphenyl)ethanimine
• CAS: 1250445-94-3
• 化学式: C₂₈H₃₃N₃O
• 分子量: 427.59
• InChiKey: SKNVRZVOPCNSAP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.7
• 重原子数：
  32
• 可旋转键数：
  5
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.32
• 拓扑面积：
  46.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  4-methoxy-2,6-diacetylpyridine 、 2,4,6-三甲基苯胺 在 甲酸 作用下， 以73%的产率得到4-methoxy-2,6-diacetylpyridine bis(2,4,6-trimethylphenylimine)
  参考文献：
  名称：

  Novel Late Transition Metal Catalysts Based on Iron: Synthesis, Structures and Ethylene Polymerization

  摘要：

  In this article we reported synthesis, characterization and ethylene polymerization behavior of two new late transition metal 2,6-bis(imino)pyridine catalysts based on iron(II) possessing different substituents of NO(2) (catalyst b) and OMe (catalyst c) at the para position of the pyridine ring. Theoretical study exhibited more positive charge on the central metal of the catalyst b, leading to higher activity offset by lower thermal stability and life time.

  DOI：

  10.1007/s10562-010-0433-x