bis(thiosaccharinato)bis(imidazole)cadmium(II) | 609769-52-0

• 分子结构分类: 有机化合物 - 苯类化合物
• 英文名称: bis(thiosaccharinato)bis(imidazole)cadmium(II)
• 英文别名: [Cd(tsac)2(im)2]
• CAS: 609769-52-0
• 化学式: C₂₀H₁₆CdN₆O₄S₄
• 分子量: 645.059
• InChiKey: BDRFGCURXZBICP-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  咪唑 、 cadmium(II) nitrate tetrhydrate 、 1,2-苯异噻唑-3-(2H)-硫酮-1,1-二氧化物 以 甲醇 为溶剂， 生成 bis(thiosaccharinato)bis(imidazole)cadmium(II)
  参考文献：
  名称：

  Structural and spectroscopic characterization of two new Cd(II) complexes: bis(thiosaccharinato)bis(imidazole) cadmium(II) and tris(thiosaccharinato)aquacadmate(II)

  摘要：

  The crystal structures of [Cd(tsac)(2)(im)(2)] (1) (tsac = anion of thiosaccharine; im = imidazole) and of (Him)[Cd(tsac)(3)(H2O)] (2) (Him = imidazolium cation) have been determined at 120 K by single crystal X-ray diffractometry. Complex 1 crystallises in the monoclinic space group P2(1)/a with Z = 4 whereas compound 2 is triclinic, space group P(- 1) and Z = 2. In both compounds, Cd(II) is in a distorted tetrahedral environment. In the neutral complex I the metal is coordinated to the Satom of the two thiosaccharinato ligands and to the N-atom of the imidazole molecules. In the anionic complex 2, Cd(II) is coordinated to three thiosaccharinato S-atoms and to the O-atom of the water molecule. The FTIR spectra of both compounds were also recorded and briefly discussed. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/s0022-2860(03)00334-x