[Cu(Me3Sn)2-(μ-pyridine-2,5-dicarboxylic acid)2]n | 1537173-15-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Cu(Me3Sn)2-(μ-pyridine-2,5-dicarboxylic acid)2]n
• 英文别名: [Cu(Me₃Sn)2-(μ-pyridine-2,5-dicarboxylic acid)₂]_n
• CAS: 1537173-15-1
• 化学式: C₂₀H₂₄CuN₂O₈Sn₂
• 分子量: 721.385
• InChiKey: JUFHZQLFLURHST-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [Cu(μ-pyridine-2,5-dicarboxylic acid)₂]_n 、 三甲基氯化锡 反应 4.0h， 生成 [Cu(Me3Sn)2-(μ-pyridine-2,5-dicarboxylic acid)2]n
  参考文献：
  名称：

  Two-Dimensional Homometallic- to a Three Dimensional Heterometallic Coordination Polymer: A Metalloligand Approach

  摘要：

  A metalloligand type of synthetic route has been followed to generate a novel heterometallic three-dimensional (3D)-coordination polymer containing Cu(II) and trimethyltin as nodes. The first step of this synthetic path consisted of the preparation of a two-dimensional-coordination polymer of Cu(II), [Cu(mu-LH)(2)](n) (1) (LH2 = pyridine-2,5-dicarboxylic add). The reaction of in situ generated 1 with Me3SnCl afforded the heterometallic 3D-coordination polymer, [Cu(Me3Sn)(2)-(mu-L)(2)](n), (2). The latter is a 4,4-connected polymer with a sqc topology. This 3D-framework contains a paddle-wheel-shaped core comprised of two heterometallic (Cu-II/Sn-IV) macrocycles.

  DOI：

  10.1021/cg401698a