iron(III) tris(4,6-di-tert-butyl-2-nitrosophenolate) | 933036-23-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: iron(III) tris(4,6-di-tert-butyl-2-nitrosophenolate)
• 英文别名: [Fe(III)(4,6-di-tert-butyl-2-nitrosophenolate)3]
• CAS: 933036-23-8
• 化学式: C₄₂H₆₀FeN₃O₆
• 分子量: 758.802
• InChiKey: PGBHMUQNKKNRCG-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  铁粉 、 4,6-di-tert-butyl-2-nitrosophenol 在 KOH or triethylamine 作用下， 以 甲醇 为溶剂， 生成 iron(III) tris(4,6-di-tert-butyl-2-nitrosophenolate)
  参考文献：
  名称：

  Coordination compounds based on 4,6-di-tert-butyl-2-nitrosophenol

  摘要：

  New metal mono-, bis-, and tris(chelates) based on 4,6-di-tert-butyl-2-nitrosophenol were synthesized and their physicochemical properties were studied. Conclusions concerning the structures of the complexes and the influence of the nature of the complexing metal on the electronic structure of the coordinated ligand were drawn from X-ray diffraction, H-1 NMR, magnetochemical, and electronic spectroscopy data.

  DOI：

  10.1134/s107032840608001x

文献信息

• Homo-and heterometal complexes with sterically eclipsed ortho-nitrosophenol
  作者：A. M. Ionov、S. N. Lyubchenko、V. A. Kogan、A. Yu. Tsivadze

  DOI：10.1134/s1070328408030081

  日期：2008.3

  Novel homo-and heterometal complexes based on 4,6-di-tert-butyl-2-nitrosophenol (HL) were synthesized, and their physicochemical properties were studied. The data of the 1H NMR, electronic spectroscopy, magnetochemical measurements, and the atomic absorption study suggest that the nitroso group of a ligand can be bidentate in polynuclear coordination compounds. The experimental data were obtained for the first time on self-assembling of both homo-and heterometal trinuclear complexes with predicted properties from the initial metal chelates of ortho-nitrosophenols.

  合成了基于 4,6-二叔丁基-2-亚硝基苯酚（HL）的新型同金属和杂金属配合物，并对其理化性质进行了研究。1H NMR、电子光谱、磁化学测量和原子吸收研究数据表明，配体的亚硝基在多核配位化合物中可以是双齿的。首次获得了同金属和杂金属三核配合物自组装的实验数据，这些配合物的性质是由正亚硝基酚的初始金属螯合物预测的。