cilianic acid | 667-88-9

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: cilianic acid
• 英文别名: Ciliansaeure；(3aS)-1ξ-Hydroxy-5-oxo-3t.5at-dimethyl-3c-(2-carboxy-aethyl)-6t-((R)-1-methyl-3-carboxy-propyl)-(3arH.8acH.8btH)-dodecahydro-as-indacen-dicarbonsaeure-(1ξ.2ξ)
• CAS: 667-88-9
• 化学式: C₂₄H₃₄O₁₀
• 分子量: 482.528
• InChiKey: YFSJQRKFJOSVMB-SJYSVYSVSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.13
• 重原子数：
  34.0
• 可旋转键数：
  9.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.79
• 拓扑面积：
  186.5
• 氢给体数：
  5.0
• 氢受体数：
  6.0

反应信息

• 作为反应物：
  描述：

  cilianic acid 在 甲醇 作用下， 生成 (3aS)-1ξ-hydroxy-5-oxo-3t-5at-dimethyl-3c-(2-methoxycarbonyl-ethyl)-6t-((R)-1-methyl-3-methoxycarbonyl-propyl)-(3arH.8acH.8btH)-dodecahydro-As-indacene-dicarboxylic acid-(1ξ.2ξ)-dimethyl ester
  参考文献：
  名称：

  Textural and chemical zoning in garnets related to mantle metasomatism and deformation processes

  摘要：

  A few texturally-zoned garnets were found in a polymict peridotite (JJG1414) from the Cretaceous kimberlite, Kimberley, South Africa. The systematic analyses of electron and ion microprobe as well as laser fluorination technique reveal the existencal of marked elemental and oxygen isotopic zonation in these garnets, corresponding to the textural zonation. The rims are normally enriched in Ca, Ti, Cr, LREE, Sr, Nb, and depleted in Mg, Al and O-18. It is demonstrated that these garnets were infiltrated by melts/fluids, probably representing the disequilibrated products of fluid-assisted mantle deformation.

  DOI：

  10.1007/bf02884668
• 作为产物：
  描述：

  bilianic acid 在 sodium hydroxide 、 potassium permanganate 作用下， 生成 cilianic acid
  参考文献：
  名称：

  Schenck, Hoppe-Seyler's Zeitschrift fur Physiologische Chemie, 1937, vol. 246, p. 258,260, 263

  摘要：

  DOI：

文献信息

• Lassar-Cohn, Chemische Berichte, 1899, vol. 32, p. 683,684
  作者：Lassar-Cohn

  DOI：——

  日期：——
• Schenck, Hoppe-Seyler's Zeitschrift fur Physiologische Chemie, 1936, vol. 244, p. 245,251
  作者：Schenck

  DOI：——

  日期：——
• Borsche; Frank, Chemische Berichte, 1927, vol. 60, p. 723,731
  作者：Borsche、Frank

  DOI：——

  日期：——
• Schenck, Hoppe-Seyler's Zeitschrift fur Physiologische Chemie, 1939, vol. 261, p. 273,277
  作者：Schenck

  DOI：——

  日期：——
• K-Ar age of the Cenozoic volcanic rocks in the Nangqen Basin, Qinghai Province and its geological significance
  作者：Wanming Deng、Hongjuan Sun、Yuquan Zhang

  DOI：10.1007/bf02884983

  日期：2000.6

  The Nangqen Basin is one of the typical shearing-extensional basins situated in the north part of the Hengduan Mts. Nine ages of the Cenozoic volcanic rocks from the basin by K-Ar isotope-dilution technique have been reported in the note. The apparent ages of whole rock and separated biotite range from 32.04 to 36.50 Ma. The Ar-40-K (%) correlation isochronal line shows that there existed neither argon excessing, or radiogenetic argon loosing, i.e. the age represents the true diagenetic time. Volcanic activity in this area occurred in the post-collision environment and is controlled by lithosphere substantial thickening and violent intercontinental shearing-strike slip faults. There is age difference of the magmatic activity in the east, the west and the north Tibet. The multi-periodic eruption-intrusion of the magmatic melt since Cenozoic is a tracer showing the pulsating uplift of the Tibetan Plateau.