| 155515-98-3

• 分子结构分类: 有机化合物 - 有机杂环化合物
• CAS: 155515-98-3
• 化学式: C₁₇H₁₅ClIrN₃O₄
• 分子量: 552.997
• InChiKey: VXHWJYRZHZACRC-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  以 盐酸 为溶剂， 生成 三氯三(吡啶)铱(III)
  参考文献：
  名称：

  Equilibria in complexes of n-heterocyclic compounds—LI. Synergic solubility and x-ray crystal structure analysis of mer-chloro-oxalato-tris-pyridine-iridium(III), [IrCl(py)3(C2O4)]

  摘要：

  The title compound, mer-[IrCl(py)(3)(C2O4)], has been made by the reaction of the known trans-dichloro-tetrapyridine-iridium(III) chloride with ethanedioate ion(oxalate) in aqueous ethanol. A non-electrolyte, it resembles its rhodium eutrope in showing extraordinary synergic solubility in water:pyridine. An X-ray structure determination has confirmed the Mer geometry.

  DOI：

  10.1016/s0277-5387(00)80040-6
• 作为产物：
  描述：

  tr-[Ir(pyridine)4Cl2]Cl*6H2O 在 potassium oxalate 作用下， 以 乙醇 、 水 为溶剂， 以58%的产率得到
  参考文献：
  名称：

  Equilibria in complexes of n-heterocyclic compounds—LI. Synergic solubility and x-ray crystal structure analysis of mer-chloro-oxalato-tris-pyridine-iridium(III), [IrCl(py)3(C2O4)]

  摘要：

  The title compound, mer-[IrCl(py)(3)(C2O4)], has been made by the reaction of the known trans-dichloro-tetrapyridine-iridium(III) chloride with ethanedioate ion(oxalate) in aqueous ethanol. A non-electrolyte, it resembles its rhodium eutrope in showing extraordinary synergic solubility in water:pyridine. An X-ray structure determination has confirmed the Mer geometry.

  DOI：

  10.1016/s0277-5387(00)80040-6