([Cu(1,4-benzenedicarboxylate)(4,4'-bipyridine)]*1,4-benzenedicarboxylic acid)n | 527673-00-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: ([Cu(1,4-benzenedicarboxylate)(4,4'-bipyridine)]*1,4-benzenedicarboxylic acid)n
• CAS: 527673-00-3
• 化学式: C₈H₆O₄*C₁₈H₁₂CuN₂O₄
• 分子量: 549.984
• InChiKey: XGYWMWBFHBBRFW-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  对苯二甲酸 、 4,4'-联吡啶 、 copper(II) nitrate trihydrate 以 水 为溶剂， 以37%的产率得到([Cu(1,4-benzenedicarboxylate)(4,4'-bipyridine)]*1,4-benzenedicarboxylic acid)n
  参考文献：
  名称：

  A porous, two-dimensional copper coordination-polymer containing guest molecules: hydrothermal synthesis, structure, and thermal property of [Cu(BDC)(bipy)](BDCH 2 ) (BDC=1,4-benzenedicarboxylate; bipy=4,4 ′ -bipyridine)

  摘要：

  The hydrothermal reaction of Cu(NO3)(2)(.)2.5H(2)O with 1,4-benzenedicarboxylic acid (BDCH2) and 4,4'-bipyridine (bipy) gave a two-dimensional copper(II) coordination polymer with an empirical of formula of [Cu(BDC)(bipy)](BDCH2) (1). Polymer 1 contains free BDCH2 molecules as guests in channels constructed by Cu, BDC2-, and bipy. The BDCH2 guest molecules are involved in intermolecular hydrogen bonds of the type O-(HO)-O-..., which seem to be main forces to hold the guests in the channels. X-ray powder diffraction (XRPD) studies suggest that polymer 1 and its guest-free form have the same framework. Polymer 1 was structurally characterized by X-ray diffraction. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s1387-7003(02)00762-1