5-(3,5-di-tert-butylphenyl)-15-(4-methoxycarbonylphenyl)-2,8,12,18-tetraethyl-3,7,13,17-tetramethylporphine zinc complex | 518297-75-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: 5-(3,5-di-tert-butylphenyl)-15-(4-methoxycarbonylphenyl)-2,8,12,18-tetraethyl-3,7,13,17-tetramethylporphine zinc complex
• CAS: 518297-75-1
• 化学式: C₅₄H₆₂N₄O₂Zn
• 分子量: 864.502
• InChiKey: GVURBXWJBRXCPA-FZYYZVSZSA-M

反应信息

• 作为产物：
  描述：

  zinc diacetate 、 以 甲醇 、 二氯甲烷 为溶剂， 以35%的产率得到5-(3,5-di-tert-butylphenyl)-15-(4-methoxycarbonylphenyl)-2,8,12,18-tetraethyl-3,7,13,17-tetramethylporphine zinc complex
  参考文献：
  名称：

  Synthesis and photoreaction of a porphyrin–Co(III)-complex linked molecule

  摘要：

  A dyad molecule composed of a zinc porphyrin and a Co(III) complex that are linked together via a coordination bond underwent intramolecular electron transfer when irradiated with visible light, and subsequent ligand exchange at the Co(II) center led to dissociation of the two moieties. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(02)01137-4