tetraphenylantimony 2,4-dimethylbenzenesulfonate | 333969-95-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: tetraphenylantimony 2,4-dimethylbenzenesulfonate
• 英文别名: Tetra-phenylantimony 2,4-dimethylbenzenesulfonate；(tetraphenyl-λ5-stibanyl) 2,4-dimethylbenzenesulfonate
• CAS: 333969-95-2
• 化学式: C₃₂H₂₉O₃SSb
• 分子量: 615.396
• InChiKey: GVGSMZRTMSQPTO-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  4.54
• 重原子数：
  37
• 可旋转键数：
  7
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  51.8
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  tetraphenylantimony 2,4-dimethylbenzenesulfonate 、 mercury(II) iodide 以 丙酮 为溶剂， 以45%的产率得到[tetraphenylstibonium]2(Hg4I10)n
  参考文献：
  名称：

  Synthesis and structures of mercury and cadmium complexes: [Ph4Sb] 2 + [Hg2I6]2−·Ph2Hg, [Ph4Sb] 2 + [E2I6]2− (E = Hg, Cd), and [Ph4Sb] 2 + [Hg4I10]2−

  摘要：

  The reaction of pentaphenylantimony with mercury iodide affords the ionic complex [Ph4Sb](2)(+)[Hg2I6](2-) center dot Ph2Hg (I). The [Ph4Sb](2)(+)[Hg2I6](2-) (II) and [Ph4Sb](2)(+)[Cd2I6](2-) (III) complexes are synthesized from tetraphenylantimony iodide and mercury and cadmium iodides. The [Ph4Sb](2)(+)[Hg4I10](2-) complex (IV) is prepared from tetraphenylantimony 2,4-dimethylbenzenesulfonate and mercury iodide. According to the X-ray diffraction data, the Sb atom in the [Ph4Sb](+) cations of complex I has virtually ideal tetrahedral coordination (the CSbC angles are 108.09 degrees-109.64 degrees). In the central square fragment Hg2I2 of the [Hg2I6](2-) anion, the Hg-I-br bond lengths are 2.825 and 3.075 angstrom, and the terminal iodine atoms are more strongly bonded to the mercury atoms (Hg-I-term 2.691 and 2.700 angstrom). The [Cd2I6](2-) anion in complex III has a similar structure (the Cd-I-bridg and Cd-I-term distances are 2.865, 2.872 and 2.723, 2.748 angstrom, respectively). The anions in complex IV are joined by I center dot center dot center dot Hg (3.651 angstrom) and I center dot center dot center dot I (4.058 angstrom) interactions into an infinite dimeric network.

  DOI：

  10.1134/s1070328407020042
• 作为产物：
  描述：

  pentaphenylantimony 、 triphenylantimony bis(2,4-dimethylbenzenesulfonate) 以 甲苯 为溶剂， 以95%的产率得到tetraphenylantimony 2,4-dimethylbenzenesulfonate
  参考文献：
  名称：

  Sharutin; Sharutina; Tarasova, Russian Journal of General Chemistry, 2000, vol. 70, # 8, p. 1229 - 1232

  摘要：

  DOI：

文献信息

• ——
  作者：V. V. Sharutin、O. K. Sharutina、I. I. Pavlushkina、I. V. Egorova、A. P. Pakusina、D. B. Krivolapov、A. T. Gubaidullin、I. A. Litvinov

  DOI：10.1023/a:1012385524010

  日期：——

  Tetraphenylantimony arenesulfonates and diphenylbismuth arenesulfonates were prepared by reaction of triphenylbismuth bis(arenesulfonates) with triphenylstibine in toluene at 25 degreesC. The crystal and molecular structure of diphenylbismuth 2,4-dimethylbenzenesulfonate was studied by single crystal X-ray diffraction. The molecules of the compound in the crystal form chains of Ph2BiOSO2C6H3Me2-2,4 fragments linked with oxygen atoms of the sulfo group of the bridging arenesulfonate ligand.
• ——
  作者：V. V. Sharutin

  DOI：10.1023/a:1023463212564

  日期：——

  Pentaarylantimony Ar3Sb (Ar = Ph, p-Tol) arylates diarylbismuth arylsulfonates Ar2BiOSO2Ar' (Ar' = C6H4Me-4; C6H3Me2-2,4, C6H3Me2-2,5) in ether at 20 degreesC (48 h) to form triarylbismuth in yields of up to 95%. The second reaction product is tetraarylantimony arenesulfonate. The reaction of pentaphenylantimony with phenylbismuth bis(arenesulfonate) PhBi(OSO2Ar')(2) under the same conditions leads to formation of diphenylbismuth arenesulfonate and tetraphenylantimony arenesulfonate in yields of up to 90%.