cyclohexyl 2-fluoro-2-propenate | 95243-51-9

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: cyclohexyl 2-fluoro-2-propenate
• 英文别名: Cyclohexyl 2-fluoroprop-2-enoate
• CAS: 95243-51-9
• 化学式: C₉H₁₃FO₂
• 分子量: 172.199
• InChiKey: OTBWUHFYKKFCDP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  12
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  cyclohexyl 2-fluoro-3-iodopropionate 在 三乙胺 作用下， 以 二氯甲烷 为溶剂， 反应 4.0h， 以74%的产率得到cyclohexyl 2-fluoro-2-propenate
  参考文献：
  名称：

  Electrochemical iodofluorination of electron-deficient olefins

  摘要：

  Electron-deficient olefins like alpha,beta-unsaturated ester, amide, and phosphonate reacted with iodonium cation species generated by the anodic oxidation of iodide anion in Et3N-5HF/CH3NO2 to form corresponding iodofluorinated compounds in good to moderate yields. The reaction proceeds at room temperature under air atmosphere and constant current conditions. The iodofluorinated products were shown to be useful fluorine-containing building blocks. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2009.11.005

文献信息

• Optical material
  申请人：DAIKIN INDUSTRIES, LIMITED

  公开号：EP0128517A2

  公开（公告）日：1984-12-19

  This invention relates to an optical material comprising a polymer which has a structural unit represented by the formula wherein X1 and X2 are the same or different and are each hydrogen or deuterium, and R1 is a chain hydrocarbon group having 1 to 5 carbon atoms, a cyclic hydrocarbon group (with or without a substituted lower alkyl group) having 3 to 6 carbon atoms or a deuterium-substituted chain hydrocarbon group having 1 to 5 carbon atoms in an amount of at least 5 mole % of the polymer.

  本发明涉及一种光学材料，该材料包含一种聚合物，其结构单元由以下式子表示 其中 X1 和 X2 相同或不同，且各自为氢或氘，R1 是具有 1 至 5 个碳原子的链烃基团、具有 3 至 6 个碳原子的环烃基团（含或不含取代的低级烷基）或具有 1 至 5 个碳原子的氘取代链烃基团，其含量至少为聚合物的 5 摩尔%。
• ELECTROLYTE, ELECTROCHEMICAL DEVICE, LITHIUM ION SECONDARY BATTERY, AND MODULE
  申请人：DAIKIN INDUSTRIES, LTD.

  公开号：EP3731329A1

  公开（公告）日：2020-10-28

  The disclosure provides an electrolyte solution capable of improving the high-temperature storage characteristics and cycle characteristics of an electrochemical device. The electrolyte solution contains at least one selected from the group consisting of a compound represented by the following formula (1-1) (wherein R101 is a group such as an optionally fluorinated C1-C7 alkyl group and optionally contains a substance such as O in the structure) and a compound represented by the following formula (1-2) (wherein R102 and R103 are (i) each individually H, F, or a group such as an optionally fluorinated C1-C7 alkyl group, or (ii) hydrocarbon groups binding to each other to form a 5-membered or 6-membered hetero ring with a nitrogen atom; and R102 and R103 each optionally contain a substance such as O in the structure).

  本公开提供了一种能够改善电化学装置的高温存储特性和循环特性的电解质溶液。该电解质溶液含有至少一种选自由下式(1-1)表示的化合物（其中 R101 是诸如任选氟化 C1-C7 烷基的基团，并在结构上任选含有诸如 O 的物质）和下式(1-2)表示的化合物（其中 R102 和 R103 (i)各自单独为 H、F，或一个基团，如任选氟化的 C1-C7 烷基，或(ii) 碳氢基团相互结合形成带有一个氮原子的 5 元或 6 元杂环；以及 R102 和 R103 结构中均可选择含有 O 等物质）。
• Plastic film, gas barrier film, and image display device using the same
  申请人：Hokazono Hirohisa

  公开号：US20060232735A1

  公开（公告）日：2006-10-19

  A plastic film comprising a multi-layer structure obtained by co-casting film formation or sequential-casting film formation of two or more layers of polyarylate having a glass transition temperature of 250° C. or higher and having a chemical structure represented by the following formula: wherein X represents a linking group having a naphthalene or biphenyl structure and A is represented by the following formula: wherein R 1 and R 2 represent an alkyl group or aryl group, j and k are an integer of from 0 to 4.

  一种塑料薄膜，其多层结构是由两层或多层玻璃化温度为 250℃或更高的聚芳酯通过共铸成膜或连续铸膜获得的，其化学结构如下式所示： 其中 X 代表具有萘或联苯结构的连接基团，A 由下式表示： 其中 R 1 和 R 2 代表烷基或芳基，j 和 k 是 0 至 4 的整数。
• JPS6333405A
  申请人：——

  公开号：JPS6333405A

  公开（公告）日：1988-02-13
• Fluorocopolymer, method for its production and resist composition containing it
  申请人：Eda Masataka

  公开号：US20070083021A1

  公开（公告）日：2007-04-12

  A fluorocopolymer having units derived from a monomer unit formed by cyclopolymerization of a fluorinated diene and units derived from a monomer unit formed by cyclopolymerization of a functional group-containing fluorinated diene having a specific structure or a monomer unit formed by polymerization of an acrylic monomer having a specific structure, a method for its production, and a resist composition.