(Cp*)Ru(CO)(bis(pyrrolidin-1-yl)methylphosphine)2 | 1333233-78-5

• 英文名称: (Cp*)Ru(CO)(bis(pyrrolidin-1-yl)methylphosphine)2
• CAS: 1333233-78-5
• 化学式: C₂₉H₅₃N₄OP₂Ru*C₃₂H₁₂BF₂₄
• 分子量: 1500.0
• InChiKey: JIYACPGIOHYROA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  一氧化碳 、 (Cp*)RuCl(bis(pyrrolidin-1-yl)methylphosphine)2 、 四(3,5-二(三氟甲基)苯基)硼酸钠 以 正己烷 为溶剂， 以86%的产率得到(Cp*)Ru(CO)(bis(pyrrolidin-1-yl)methylphosphine)2
  参考文献：
  名称：

  Ruthenium piano-stool complexes containing mono- or bidentate pyrrolidinylalkylphosphines and their reactions with small molecules

  摘要：

  Ruthenium piano-stool complexes incorporating the new bidentate aminoalkylphosphine ligand 1,2-bis(dipyrrolidin-1-ylphosphino) ethane (dpyrpe, I) or its monodentate counterpart bis(pyrrolidin-1-yl) methylphosphine (pyr(2)PMe, II) have been prepared, [(C5R5)RuCl(PP)] (R = Me and PP = dpyrpe, 1; R = Me and PP = (pyr(2)PMe)(2), 2; R = H and PP = dpyrpe, 3). Complexes 2 and 3 have been characterized by X-ray crystallography. Complexes 1 and 2 react with NaBAr4f in the presence of ligand L to yield [Cp*Ru(L)(dpyrpe-kappa P-2)][BAr4f] (L = MeCN, 4a; CO, 4b; N-2, 4c) and [Cp*Ru(L)(pyr(2)PMe)(2)][BAr4f] (L = MeCN, 5a; CO, 5b; N-2, 5c). Complex 4a was crystallographically characterized. The CO complexes 4b and 5b were examined using IR spectroscopy in an attempt to establish the electron-donating capabilities of I and II. Complex 1 oxidatively adds H-2 in the presence of NaBAr4f to yield the Ru(IV) dihydride [Cp*RuH2(dpyrpe-kappa P-2)][BAr4f], 7. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2011.06.037