Ru(III)(salen)(PPh3)Cl | 65849-07-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Ru(III)(salen)(PPh3)Cl
• 英文别名: [Ru(triphenylphosphine)Cl(N,N'-ethan-1,2-diylbis(salicylideneamine)]；[Ru(triphenylphosphine)Cl(salen)]；Ru(salen)(triphenylphosphine)Cl；[Ru(N,N'-ethane-1,2-diylbis(salicylidenamine))(triphenylphosphine)(Cl)]；[Ru(salen)(PPh3)(Cl)]；RuCl(PPh3)(SALEN)
• CAS: 65849-07-2
• 化学式: C₃₄H₂₉ClN₂O₂PRu
• 分子量: 665.113
• InChiKey: FYIZFBSFZZRSHM-STOXJSFMSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Ru(III)(salen)(PPh3)Cl 在 NaCN 作用下， 以 甲醇 为溶剂， 以50%的产率得到Na{Ru(III)(salen)(CN)2}
  参考文献：
  名称：

  Leung, Wa-Hung; Che, Chi-Ming, Inorganic Chemistry, 1989, vol. 28, # 26, p. 4619 - 4622

  摘要：

  DOI：
• 作为产物：
  描述：

  tris(triphenylphosphine)ruthenium(II) chloride 、 N,N'-双(亚水杨基)乙二胺 在 三乙胺 作用下， 以 四氢呋喃 为溶剂， 以76%的产率得到Ru(III)(salen)(PPh3)Cl
  参考文献：
  名称：

  席夫碱和三苯基膦配体负载的钌（III）的合成，结构和催化醇氧化

  摘要：

  用两个当量对[RuCl2（PPh3）3]进行抽象处理。双齿席夫碱N，O-LH-Cl（N，O-LH-Cl = 2 [（3-氯-苯基亚氨基）-甲基]-苯酚）或N，O-LH-NO2（N，O-LH -NO2 = 2 [（（4-硝基-苯基亚氨基）-甲基]-苯酚）在三乙胺的存在下提供顺式-[RuCl（PPh3）（κ2-N，OL-Cl）2]（1）和反式-[RuCl （PPh3）（κ2-N，OL-NO2）2]·Et2O（2）。[RuCl2（PPh3）3]与等当量的反应。四齿席夫碱得到相应的钌（III）络合物[RuCl（PPh3）（salen）]（3）（H2salen = N，N'-二水杨基-1,2-乙二胺），[RuCl（PPh3）（salipn）] ·2CH2Cl2（4）（H2salipn = N，N'-二水杨基-1,2-（1-甲基）乙二胺），[RuCl（PPh3）（salpn）]·CH2Cl2（5）（H2salpn

  DOI：

  10.1016/j.ica.2018.03.017
• 作为试剂：
  描述：

  5-甲氧基-2-[[(4-甲氧基-3,5-二甲基-2-吡啶基)甲基]硫代]-1H-苯并咪唑N-氧化物 在 Ru(III)(salen)(PPh3)Cl 碘苯 、 silver(I) acetate 作用下， 以 二氯甲烷 为溶剂， 生成 奥美拉唑
  参考文献：
  名称：

  PROCESS FOR THE PREPARATION OF PYRIDINE COMPOUNDS

  摘要：

  一种制备式(I)化合物的方法，包括其同分异构体混合物和单个异构体，其中Q为═CR8—或═N—；每个R1、R2、R3、R4独立选择自氢、卤素、羟基、硝基、C1-C6烷基（可选用羟基取代）、C1-C6烷基硫醇、C1-C6烷氧基（可选用卤素或C1-C6烷氧基取代）、苯基-C1-C6烷基、苯基-C1-C6烷氧基和—N(RaRb)（其中每个Ra和Rb独立选择自氢或C1-C6烷基，或Ra和Rb连同它们链接到的氮原子形成饱和杂环环）；每个R5、R6、R7、R8独立选择自氢、卤素、羟基、C1-C6烷基（可选用羟基取代）、C1-C6烷基硫醇、C1-C6烷氧基（可选用卤素取代）、C1-C6烷基-羰基、C1-C6烷氧基-羰基和噁唑-2-基；包括在有机溶剂中，在催化剂的存在下，将式(IV)化合物转化为所述式(I)化合物，必要时使用催化剂。

  公开号：

  US20070249662A1

文献信息

• Ferromagnetic interactions in Ru(<scp>iii</scp>)–nitronyl nitroxide radical complex: a potential 2p4d building block for molecular magnets
  作者：Fabrice Pointillart、Kevin Bernot、Lorenzo Sorace、Roberta Sessoli、Dante Gatteschi

  DOI：10.1039/b701657c

  日期：——

  The reaction between [Ru(salen)(PPh3)Cl] and the 4-pyridyl-substituted nitronyl nitroxide radical (NITpPy) leads to the [Ru(salen)(PPh3)(NITpPy)](ClO4)(H2O)21 complex while the reaction with the azido anion (N3−) leads to the [Ru(salen)(PPh3)(N3)] 2 complex (where salen2− = N,N′-ethan-1,2-diylbis(salicylidenamine) and PPh3 = triphenylphosphine). Both compounds have been characterized by single crystal X-ray diffraction. The two crystal structures are composed by a [Ru(III)(salen)(PPh3)]+ unit where the Ru(III) ion is coordinated to a salen2− ligand and one PPh3 ligand in axial position. In 1 the Ru(III) ion is coordinated to the 4-pyridyl-substituted nitronyl nitroxide radical whereas in 2 the second axial position is occupied by the azido ligand. In both complexes the Ru(III) ions are in the same environment RuO2N3P, in a tetragonally elongated octhaedral geometry. The crystal packing of 1 reveals π-stacking in pairs. While antiferromagnetic intermolecular interaction (J2 = 5.0 cm−1) dominates at low temperatures, ferromagnetic intramolecular interaction (J1 = −9.0 cm−1) have been found between the Ru(III) ion and the coordinated NITpPy.

  Ru(salen)(PPh3)Cl]与 4-吡啶基取代的硝基亚硝氧自由基（NITpPy）反应生成[Ru(salen)(PPh3)(NITpPy)](ClO4)(H2O)21 复合物，而与叠氮阴离子（N3â）反应则生成[Ru(salen)(PPh3)(N3)] 2 复合物（其中 salen2â = N、Nâ²-ethan-1,2-diylbis(salicylidenamine) 和 PPh3 = 三苯基膦）。这两种化合物都已通过单晶 X 射线衍射法进行了表征。这两种晶体结构都由一个 [Ru(III)(salen)(PPh3)]+ 单元组成，其中 Ru(III) 离子与一个 salen2â 配体和一个 PPh3 配体配位在轴向位置。在 1 中，Ru(III) 离子与 4-吡啶基取代的硝基硝氧自由基配位，而在 2 中，第二个轴向位置被叠氮配体占据。在这两种配合物中，Ru（III）离子都处于相同的 RuO2N3P 环境中，呈四方拉长的八面体几何形状。1 的晶体堆积显示出成对的Ï-堆积。虽然分子间的反铁磁作用（J2 = 5.0 cmâ1）在低温下占主导地位，但在 Ru（III）离子和配位的 NITpPy 之间发现了铁磁分子内作用（J1 = 9.0 cmâ1）。
• First Paramagnetic 4d Transition-Metal Complex with a Redox-Active Tetrathiafulvalene Derivative, [Ru(salen)(PPh₃)(TTF-CH═CH-Py)]BF₄ [salen²⁻ = <i>N</i>,<i>N</i>′-Ethan-1,2-diylbis(salicylidenamine), PPh₃ = Triphenylphosphine, TTF-CH═CH-Py = 4-(2-Tetrathiafulvalenylethenyl)pyridine]
  作者：Fabrice Pointillart、Yann Le Gal、Stéphane Golhen、Olivier Cador、Lahcène Ouahab

  DOI：10.1021/ic801340k

  日期：2008.11.3

  The first paramagnetic 4d transition-metal complex with a redox-active tetrathiafulvalene ligand has been synthesized. The preparation, X-ray structure, electrochemistry, and electron paramagnetic resonance measurements of [Ru(salen)(PPh3)(TTF-CH=CH-Py)](BF4) [1(BF4)] are reported. The crystal structure reveals that the paramagnetic Ru-III (s = 1/2) center is in a tetragonally elongated octahedral geometry and the TTF-CH=CH-Py ligand is coordinated to the axial position of the Ru-III ion through the nitrogen atom of the pyridine group. Thus, 1 (BF4) is an attractive precursor to study future pi-4d interactions in dual-property conducting and magnetic materials.
• Rational enhancement of the coordination capability of Ru(III)(salen)-nitronyl nitroxide building block: A step towards 2p–3d–4d magnetic edifices
  作者：Fabrice Pointillart、Kevin Bernot、Jeremy Colas、Lorenzo Sorace、Roberta Sessoli

  DOI：10.1016/j.ica.2008.02.047

  日期：2008.9

  The reaction of [Ru(salen)(PPh3)Cl] and the 5-imidazol-substituted nitronyl nitroxide radical (NIT(5)ImH) yields the [Ru(salen)(PPh3)(NIT-(5)ImH)](ClO4) (1) complex which has been characterized by single crystal X-ray diffraction. This analysis reveals that the Ru(III) ion is coordinated to a tetradentate salen(2) ligand in equatorial positions while one PPh3 ligand and one NIT-(5) ImH radical are coordinated in axial positions. This led to Ru-III ions in tetragonally elongated octahedral geometry. From the magnetic point of view ferromagnetic intramolecular interaction (J(1) = + 2.47 cm (1)) have been found between the Ru(III) ion and the coordinated NIT-(5)ImH while no significant intermolecular antiferromagnetic interactions are observed at low temperature leading to a ground spin state S = 1. The absence of intermolecular magnetic interaction is explained by considering the crystal packing of (1) where the [Ru(salen)(PPh3)(NIT-(5)ImH)](+) moieties are relatively well isolated. This has to be compared with the situation observed in the previously reported [Ru(salen)(PPh3)-(NIT)](+) compound (2) where ferromagnetic Ru-III-NIT interaction were identified and the crystal packing generate intermolecular antiferromagnetic interactions that complicated the study. The analysis of this compound confirms the rather isotropic g values that were found of (2) and of [Ru(salen)(PPh3)(N-3)], (3) a radical-free analogue. Moreover it is also a step towards extended structures based on Ru-III-NIT moieties since this compound possesses a free bischelating site likely to coordinate additional metallic ions. (c) 2008 Elsevier B. V. All rights reserved.
• Synthesis and Ferromagnetic Spin-Coupling of a Imidazolate-Bndged 3<i>d</i>-4<i>d</i>Cu(II)-Ru(III) Binuclear Complex
  作者：Keiji Inoue、Naohide Matsumoto、Hisashi Okawa

  DOI：10.1246/cl.1993.1433

  日期：1993.8

  A 3d-4d binuclear Cu(II)-Ru(III) complex exhibiting ferromagnetic spin-coupling [Cu(A)Ru(salen)(PPh3)]ClO4·MeOH has been synthesized and characterized, where H2A = N-(2-imidazolidene)-N′-(acetylacetonylidene)ethylendiamine and H2salen = N,N′-bis(salicylidene)ethylenediamine. The magnetic susceptibility data (4.2–300 K) were well reproduced by the equation derived from H = −2JSCu·SRu (SCu = 1/2, SRu = 1/2) with g = 2.04 and J = +6.55 cm−1. The ESR study indicated that the magnetic orbitals of Cu(II) and Ru(III) are orthogonal to each other.