[Zr(NMe2)3(THF)2][BPh4] | 192136-54-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Zr(NMe2)3(THF)2][BPh4]
• CAS: 192136-54-2
• 化学式: C₁₄H₃₄N₃O₂Zr*C₂₄H₂₀B
• 分子量: 686.901
• InChiKey: FXBOJTXMAMENQE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  triethylammonium tetraphenylborate 、 四氢呋喃 、 tetrakis(dimethylamido)zirconium 以 四氢呋喃 为溶剂， 以97%的产率得到[Zr(NMe2)3(THF)2][BPh4]
  参考文献：
  名称：

  Synthesis of cationic Group 4 metal compounds by protonolysis of amide precursors: crystal structure of [Ti(NMe2)3(NC5H5)2][BPh4]

  摘要：

  Protonation of [M(NMe2)(4)] with NHEt3BPh4 in tetrahydrofuran (THF) gave the cationic compounds [M(NMe2)(3)(THF)(x)][BPh4] (M = Ti and x = 1; M = Zr or Hf and x = 2); similar treatment of [M(cp)(2)(NMe2)(2)] (M = Zr or Hf, cp = eta-C5H5) afforded the cations [M(cp)(2)(NMe2)(NMe2H)(1-x)(THF)(x)](+) which were transformed into [M(cp)(2)(NMe2)(NC5H5)](+) in pyridine. The trigonal bipyramidal crystal structure of [Ti(NMe2)(3)(NC5H5)(2)][BPh4] has been determined.

  DOI：

  10.1016/s0022-328x(96)06701-0

文献信息

• Pentaarylfullerenes as Noncoordinating Cyclopentadienyl Anions
  作者：Marco W. Bouwkamp、Auke Meetsma

  DOI：10.1021/ic802034m

  日期：2009.1.5

  The first example of an early-transition-metal complex involving a pentaarylfullerene was prepared. Instead of half-sandwich complexes, solvent separated ion pairs were obtained in which the pentaarylfullerene moiety acts as noncoordinating cyclopentadienyl anion.