1,3-dihydro-8'-(2,3,6,7-tetrahydro-8-hydroxy-1H,5H-benzo[ij]quinolizin-9-ylmethylenimino)-1,3,3-trimethylspiro[2H-indol-2,3'-[3H]naphtho[2,1-b][1,4]oxazine] | 1263432-02-5

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: 1,3-dihydro-8'-(2,3,6,7-tetrahydro-8-hydroxy-1H,5H-benzo[ij]quinolizin-9-ylmethylenimino)-1,3,3-trimethylspiro[2H-indol-2,3'-[3H]naphtho[2,1-b][1,4]oxazine]
• CAS: 1263432-02-5
• 化学式: C₃₅H₃₄N₄O₂
• 分子量: 542.681
• InChiKey: HLKVZPQFAJZSDY-UHFFFAOYSA-N

物化性质

• 熔点：
  204-205 °C
• 沸点：
  801.4±65.0 °C(predicted)
• 密度：
  1.32±0.1 g/cm3(Temp: 20 °C; Press: 760 Torr)(predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.21
• 重原子数：
  41.0
• 可旋转键数：
  2.0
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.31
• 拓扑面积：
  60.66
• 氢给体数：
  1.0
• 氢受体数：
  6.0

反应信息

• 作为反应物：
  描述：

  1,3-dihydro-8'-(2,3,6,7-tetrahydro-8-hydroxy-1H,5H-benzo[ij]quinolizin-9-ylmethylenimino)-1,3,3-trimethylspiro[2H-indol-2,3'-[3H]naphtho[2,1-b][1,4]oxazine] 以 甲苯 为溶剂， 生成 、
  参考文献：
  名称：

  Dynamics of photoprocesses in novel bifunctional salicylideneiminospironaphthoxazines

  摘要：

  The dynamics of photochemical processes in a number of novel photobifunctional compounds, whose molecules combine a photochromic spironaphthoxazine fragment with the salicylideneimine moiety containing different substituents, was studied by the flash photolysis technique. Three products of photolysis of these compounds were detected, and the effects of the substituents and the solvent nature (toluene and methanol) on their spectral and kinetic characteristics and quantum yields were studied.

  DOI：

  10.1134/s0018143910020086
• 作为产物：
  描述：

  8-羟基久洛尼定-9-甲醛 、 1,3-dihydro-8'-amino-1,3,3-trimethylspiro{2H-indole-2,3'-(3H)-naphtho[2,1-b][1,4]oxazine} 以 甲苯 为溶剂， 反应 14.0h， 以11.4%的产率得到1,3-dihydro-8'-(2,3,6,7-tetrahydro-8-hydroxy-1H,5H-benzo[ij]quinolizin-9-ylmethylenimino)-1,3,3-trimethylspiro[2H-indol-2,3'-[3H]naphtho[2,1-b][1,4]oxazine]
  参考文献：
  名称：

  Dynamics of photoprocesses in novel bifunctional salicylideneiminospironaphthoxazines

  摘要：

  The dynamics of photochemical processes in a number of novel photobifunctional compounds, whose molecules combine a photochromic spironaphthoxazine fragment with the salicylideneimine moiety containing different substituents, was studied by the flash photolysis technique. Three products of photolysis of these compounds were detected, and the effects of the substituents and the solvent nature (toluene and methanol) on their spectral and kinetic characteristics and quantum yields were studied.

  DOI：

  10.1134/s0018143910020086