cadmium(II)(thiocarbamide)2(acetato)2 | 19596-70-4

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机含氧阴离子化合物
• 英文名称: cadmium(II)(thiocarbamide)2(acetato)2
• 英文别名: [Cd(thiourea)2(acetate)2]；[Cd(thio)2(ac)2]；cadmium(2+);thiourea;diacetate
• CAS: 19596-70-4；59926-99-7；73494-78-7
• 化学式: C₆H₁₄CdN₄O₄S₂
• 分子量: 382.744
• InChiKey: RJQOJOGJAJKGTQ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  bis-thiourea zinc acetate 、 cadmium(II)(thiocarbamide)2(acetato)2 以 neat (no solvent) 为溶剂， 生成 cadmium zinc sulfide
  参考文献：
  名称：

  Thiourea complexes in synthesis of Cd1 − x Zn x S solid solutions

  摘要：

  Solid solutions of the CdS-ZnS system deposited as polycrystalline films by aerosol pyrolysis from aqueous solutions of cadmium and zinc thiourea complexes have been studied. The phase composition and solid-phase solubility are dictated by the nature of initial complexes. From solutions of [M(thio)(2)(CH3COO)(2)] complexes, sphalerite sulfides are precipitated, which form a continuous solid solution s-Cd1-x Zn (x) S, whereas the use of the [M(thio)(2)Cl-2] precursor leads to crystallization of the wurtzite w-Cd1-x Zn (x) S solid solution based on CdS (the homogeneity range 0-20 mol % ZnS) and the s-Cd1-x Zn (x) S solid solution based on zinc sulfide (50-100 mol % ZnS). The structure of the solid phase in the sulfide system is attributed to the specific features of the stereochemistry of complex precursors.

  DOI：

  10.1134/s0036023611040218
• 作为产物：
  描述：

  cadmium(II) acetate 、 硫脲 以 水 为溶剂， 生成 cadmium(II)(thiocarbamide)2(acetato)2
  参考文献：
  名称：

  Structure and properties of thiocarbamide complexes of cadmium and zinc according to the results of a quantum-chemical calculation

  摘要：

  Quantum-chemical simulation of the structure and some properties of thiocarbamide complexes of cadmium was performed. The energy effects of dissociation in a vacuum and aqueous solutions were evaluated and the charge distribution, vibration frequencies of cadmium and zinc complexes, and a number of their electronic characteristics were calculated.

  DOI：

  10.1134/s107042721006008x

文献信息

• UGAJ, YA. A.;SEMENOV, V. N.;AVERBAX, E. M.;SHAMSHEEVA, I. L., ZH. PRIKL. XIMII, 61,(1988) N 11, S. 2409-2414
  作者：UGAJ, YA. A.、SEMENOV, V. N.、AVERBAX, E. M.、SHAMSHEEVA, I. L.

  DOI：——

  日期：——