2-tributylstannyl-5-[(5-tributylstannylthien-2-yl)methyl]thiophen | 364328-97-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 杂芳族化合物
• 英文名称: 2-tributylstannyl-5-[(5-tributylstannylthien-2-yl)methyl]thiophen
• CAS: 364328-97-2
• 化学式: C₃₃H₆₀S₂Sn₂
• 分子量: 758.391
• InChiKey: ZQVGUIYDHKDJBP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.99
• 重原子数：
  37
• 可旋转键数：
  8
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.58
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2-(2-噻吩甲基)噻吩 、 三丁基氯化锡 在 C₄H₉Li 作用下， 以 乙醚 、 正己烷 为溶剂， 以33%的产率得到2-tributylstannyl-5-[(5-tributylstannylthien-2-yl)methyl]thiophen
  参考文献：
  名称：

  The synthesis and characterisation of C-triorganometallated (metal=Sn, Si) bis-(thienyl)- and bis-(pyrazolyl)alkanes, including the crystal structure of [(Ph3Sn)C3N2]2CH2

  摘要：

  C-organostannyl- and organosilyl-derivatives of 2-(thien-2-ylmethyl)thiophene and 1-[(1H-pyrazol-1-yl)methyl]-1H-pyrazole have been synthesised and characterised spectroscopically. Lithiation and subsequent substitution by R3M takes place at the 5,5' positions for both bis-heterocycles, and this is confirmed by the X-ray structure of 1,1'-[5,5'-(Ph3Sn)C3N2](2)CH2. (C) 2001 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(01)00799-9

文献信息

• The synthesis and characterisation of C-triorganometallated (metal=Sn, Si) bis-(thienyl)- and bis-(pyrazolyl)alkanes, including the crystal structure of [(Ph3Sn)C3N2]2CH2
  作者：Michael S. Hill、Mary F. Mahon、John M.G. McGinley、Kieran C. Molloy

  DOI：10.1016/s0277-5387(01)00799-9

  日期：2001.6

  C-organostannyl- and organosilyl-derivatives of 2-(thien-2-ylmethyl)thiophene and 1-[(1H-pyrazol-1-yl)methyl]-1H-pyrazole have been synthesised and characterised spectroscopically. Lithiation and subsequent substitution by R3M takes place at the 5,5' positions for both bis-heterocycles, and this is confirmed by the X-ray structure of 1,1'-[5,5'-(Ph3Sn)C3N2](2)CH2. (C) 2001 Elsevier Science Ltd. All rights reserved.