2-Butyl-6-tert.-butyl-phenol | 22496-48-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-Butyl-6-tert.-butyl-phenol
• 英文别名: 2-Butyl-6-tert-butylphenol
• CAS: 22496-48-6
• 化学式: C₁₄H₂₂O
• 分子量: 206.328
• InChiKey: JLBMJOPTDAAHQS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  15
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  2-tert-Butyl-6-(1-methyl-allyl)-phenol 在 palladium on activated charcoal 氢气 、 N,N-二乙基苯胺 作用下， 生成 2-Butyl-6-tert.-butyl-phenol
  参考文献：
  名称：

  关于芳烃CLAISEN重排的立体化学

  摘要：

  讨论了可能的过渡态构象（椅子（S），船形（W）和扭曲形（T），分别是十字形（K）形式）及其在烯丙基芳基醚的热邻位-CLAISEN重排中的确定方法。

  DOI：

  10.1002/hlca.19690520141

文献信息

• 3,5-Dialkyl-4-hydroxyphenyl-substituted derivatives
  申请人：The B.F. GOODRICH Company

  公开号：EP0141419A1

  公开（公告）日：1985-05-15

  3,5-dialkyl-4-hydroxyphenyl-substituted amides, acetic acids and acetic acid esters are novel stabilizers for organic materials subject to attack and degradation by heat, oxygen and light, and form useful combinations for this purpose with other hindered phenol stabilizers, hindered amine stabilizers, phosphite stabilizers, and o-hydroxy- benophenone stabilizers.

  3,5-二烷基-4-羟基苯基取代酰胺、乙酸和乙酸酯是一种新型稳定剂，适用于受热、氧和光侵蚀和降解的有机材料，并为此与其他受阻酚稳定剂、受阻胺稳定剂、亚磷酸酯稳定剂和邻羟基苯甲酮稳定剂形成有用的组合。
• N-(substituted-1-piperazinealkyl)-alpha-(3,5-di-alkyl-4-hydroxyphenyl)-alpha,alpha-dialkyl acetamides
  申请人：THE B.F. GOODRICH COMPANY

  公开号：EP0258598A2

  公开（公告）日：1988-03-09

  N-(substituted cyclic alkyleneimine)-a-3,5-di-alkyl-4-hydroxyphenyl)-a', α"-dialkyl acetamides prepared by a new process are novel stabilizers for organic materials subject to attack and degradation, and form useful combinations for this purpose with other stabilizers against attack of polymer materials by heat, oxygen and light.

  用一种新工艺制备的 N-（取代的环亚烷基亚胺）-a-3,5-二烷基-4-羟基苯基）-a', α"-二烷基乙酰胺是一种新型稳定剂，适用于受侵蚀和降解的有机材料，并为此与其他稳定剂形成有用的组合，防止聚合物材料受热、氧和光的侵蚀。
• N-(substituted piperidinyl)-alpha-(3,5-dialkyl-4-hydroxyphenyl)-alpha', alpha''-dialkyl acetamides
  申请人：THE B.F. GOODRICH COMPANY

  公开号：EP0284800A1

  公开（公告）日：1988-10-05

  N-(2,2,6,6-tetraalkyl-4-piperidinyl)-α-(3,5-­di-alkyl-4-hydroxyphenyl)-αʹ,αʺ-dialkylacetamides are prepared by a new process are novel stabilizers for or­ganic materials subject to attack and degradation, and form useful combinations for this purpose with other stabilizers against attack of polymer materials by heat, oxygen and light.

  通过一种新工艺制备的 N-(2,2,6,6-四烷基-4-哌啶基)-α-(3,5-二烷基-4-羟基苯基)-αʹ,αʺ-二烷基乙酰胺是一种新型稳定剂，可用于受侵蚀和降解的有机材料，并为此与其他稳定剂形成有用的组合，防止聚合物材料受热、氧和光的侵蚀。
• POLYVINYL CHLORIDE RESIN COMPOSITIONS AND MANUFACTURING METHOD THEREFOR
  申请人：Kuraray Co., Ltd.

  公开号：EP2348070A1

  公开（公告）日：2011-07-27

  A polyvinyl chloride resin composition contains: from 0.005 to 5 parts by weight of a polyvinyl alcohol having a viscosity average degree of polymerization of from 100 to 3000 and having a ratio Mw/Mn of a weight average molecular weight Mw to a number average molecular weight Mn of from 2.2 to 4.9; and from 0.01 to 5 parts by weight of a zinc compound, based on 100 parts by weight of a polyvinyl chloride resin. A polyvinyl chloride resin composition is thereby provided that enables to obtain a shaped article thereof excellent in thermal stability while being shaped and less colored.

  一种聚氯乙烯树脂组合物含有：0.005 至 5 重量份的聚乙烯醇，其粘度平均聚合度为 100 至 3000，重量平均分子量 Mw 与数量平均分子量 Mn 之比为 2.2 至 4.9；以及 0.01 至 5 重量份的锌化合物（以 100 重量份的聚氯乙烯树脂为基准）。本发明提供了一种聚氯乙烯树脂组合物，可以获得热稳定性极佳的成型制品，同时还能减少着色。
• 1,2-ALKANE POLYOL-CONTAINING COMPOSITION
  申请人：Osaka Organic Chemical Ind., Ltd.

  公开号：EP2985017A1

  公开（公告）日：2016-02-17

  Provided is a composition containing, as an alkane polyol, a C4-18 1,2-alkane polyol in which the degradation over time of the C4-18 1,2-alkane polyol, which has inferior chemical stability and degrades easily, is suppressed, the composition being suitable for use in a cosmetic, an inkjet ink, a fiber or a coating material such as a paint. A composition containing 1,2-alkane polyol that can be used in a cosmetic, an inkjet ink, a raw material for fibers or a coating material, the alkane polyol being a C4-18 1,2-alkane polyol, and the composition containing a radical scavenger.

  本发明提供了一种含有 C4-18 1,2-烷烃多元醇作为烷烃多元醇的组合物，在该组合物中，化学稳定性较差且容易降解的 C4-18 1,2-烷烃多元醇随时间推移的降解受到抑制，该组合物适用于化妆品、喷墨墨水、纤维或涂料等涂层材料。一种含有 1,2-烷烃多元醇的组合物，可用于化妆品、喷墨墨水、纤维原料或涂层材料，烷烃多元醇为 C4-18 1,2-烷烃多元醇，组合物中含有自由基清除剂。