[(bis-mercaptoethanediazacyclooctane)Pb(II)]2 | 777067-56-8

• 分子结构分类: 有机化合物
• 英文名称: [(bis-mercaptoethanediazacyclooctane)Pb(II)]2
• CAS: 777067-56-8
• 化学式: C₂₀H₄₀N₄Pb₂S₄
• 分子量: 879.228
• InChiKey: PJEKBHKKDBBCAM-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  zinc acetylacetonate hydrate 、 [(bis-mercaptoethanediazacyclooctane)Pb(II)]2 以 甲醇 为溶剂， 生成 [(bis-mercaptoethanediazacyclooctane)Zn]2
  参考文献：
  名称：

  Accommodation of the Irregular Coordination Geometry of Lead(II) by a Square Planar N₂S₂ Ligand and Its Preference for Zinc(II)

  摘要：

  The N2S2 ligand, bis-mercaptoethanediazacyclooctane, coordinates to Pb(II) largely through sulfur donors, enlisting a second unit to fulfill an irregular, hemispherical N2S3 coordination environment in which a void suggests the location of a stereochemically active lone pair on Pb(II). That the highly exposed lead is vulnerable to metal ion displacement is demonstrated on reaction with zinc which results in a regular square pyramidal coordination about zinc within a [N2S2Zn](2) dimer. Analysis of the two dimeric structures finds different connectivities of the monomeric subunits account for the stability of the zinc structure over that of the lead.

  DOI：

  10.1021/ic049489d
• 作为产物：
  描述：

  lead(II) acetylacetonate 、 1,5-bis(2-mercaptoethyl)-1,5-diazacyclooctane 以 甲醇 、 甲苯 为溶剂， 生成 [(bis-mercaptoethanediazacyclooctane)Pb(II)]2
  参考文献：
  名称：

  Accommodation of the Irregular Coordination Geometry of Lead(II) by a Square Planar N₂S₂ Ligand and Its Preference for Zinc(II)

  摘要：

  The N2S2 ligand, bis-mercaptoethanediazacyclooctane, coordinates to Pb(II) largely through sulfur donors, enlisting a second unit to fulfill an irregular, hemispherical N2S3 coordination environment in which a void suggests the location of a stereochemically active lone pair on Pb(II). That the highly exposed lead is vulnerable to metal ion displacement is demonstrated on reaction with zinc which results in a regular square pyramidal coordination about zinc within a [N2S2Zn](2) dimer. Analysis of the two dimeric structures finds different connectivities of the monomeric subunits account for the stability of the zinc structure over that of the lead.

  DOI：

  10.1021/ic049489d