[Ru(PPh3)2(2-(acetoacetoxy)ethyl methacrylate-anion)2] | 461677-48-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Ru(PPh3)2(2-(acetoacetoxy)ethyl methacrylate-anion)2]
• CAS: 461677-48-5
• 化学式: C₅₆H₅₆O₁₀P₂Ru
• 分子量: 1052.07
• InChiKey: JAFFKEMVWRUKLL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  tris(triphenylphosphine)ruthenium(II) chloride 、 乙酰乙酸甲基丙烯酸乙二醇酯 在 三乙胺 作用下， 以 乙醇 为溶剂， 以68%的产率得到[Ru(PPh3)2(2-(acetoacetoxy)ethyl methacrylate-anion)2]
  参考文献：
  名称：

  Synthesis and copolymerization of a ruthenium(II) complex with the deprotonated form of 2-(acetoacetoxy)ethylmetacrylate

  摘要：

  The new polymerizable complex Ru(PPh3)(2)(AAEMA)(2) was obtained by reaction of RUCl2(PPh3)(3) with the anion of 2(acetoacetoxy)ethylmethacrylate (AAEMA(-)). The complex was characterized by NMR, IR, UV-Vis, mass spectrometry and cyclic voltammetry techniques. In order to obtain a supported metal complex suitable for catalytic applications, Ru(PPh3)2(AAEMA)2 was copolymerized with N,N-dimethylacrylamide as comonomer and N,N'-methylenebisacrylamide as cross-linker. The obtained insoluble resin [Ru-pol] was characterized by elemental analyses, IR, UV-Vis and CP/MAS P-31 {H-1} NMR techniques. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(02)00832-0