The present invention relates to a process for preparing a rubber containing polymer bound antidegradants. The process comprises the aqueous emulsion polymerization of (a) at least one functionalized monomer that contains an antidegradant moiety and a polymerizable vinyl group; with (b) at least one copolymerizable conjugated diene monomer, wherein the polymerization is conducted in the presence of from about 1 to about 70 parts by weight of an ester based on 100 parts by weight of total monomers. The ester functions as a synergist for the antidegradant, as a cosolvent/dispersing agent for the antidegradant during emulsion polymerization and as a plasticizer for the final polymer product.
本发明涉及一种制备含有与抗降解剂结合的聚合物的橡胶的工艺。该工艺包括:(a) 至少一种含有防降解剂分子和可聚合
乙烯基的官能化单体;(b) 至少一种可共聚的共轭二烯单体的
水乳液聚合,其中聚合是在以 100 份单体总重量为基准,加入约 1 至约 70 份(重量)酯的情况下进行的。
酯类可作为抗降解剂的增效剂、乳液聚合过程中抗降解剂的共溶剂/分散剂以及最终聚合物产品的
增塑剂。