(4-Vinyl-benzyl)-propyl-ether | 16251-36-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (4-Vinyl-benzyl)-propyl-ether
• 英文别名: p-Vinylbenzyl-n-propylether；p-Vinylbenzyl-propylether；1-Ethenyl-4-(propoxymethyl)benzene
• CAS: 16251-36-8
• 化学式: C₁₂H₁₆O
• 分子量: 176.258
• InChiKey: ONAPANYTKAAEAP-UHFFFAOYSA-N

物化性质

• 沸点：
  87-88 °C(Press: 3 Torr)
• 密度：
  0.9462 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  13
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  (4-Vinyl-benzyl)-propyl-ether 在 N-溴代丁二酰亚胺(NBS) 、 ammonium acetate 作用下， 以 水 、 丙酮 为溶剂， 反应 5.0h， 以78%的产率得到2-bromo-1-(4-(n-propoxymethyl)phenyl)ethan-1-ol
  参考文献：
  名称：

  含醚部分恶唑啉的设计、合成、杀螨活性和构效关系研究

  摘要：

  为了开发高效、低成本的杀螨剂，由不同的醇和酚合成了一系列在 4-苯基对位含有醚部分的 2,4-二苯基-1,3-恶唑啉。生物测定结果表明，大多数化合物，尤其是短链烷基醚，对朱砂叶螨的幼虫和卵均表现出优异的杀螨活性。特别是，正丙醚化合物Ic的杀幼虫活性 (LC 50 = 0.0015 mg/L) 和杀卵活性 (LC 50 = 0.0008 mg/L) 比商品杀螨剂乙恶唑 (LC 50= 0.0145 和 0.02 mg/L 的幼虫和卵，分别）。此外，一些化合物还表现出杀虫活性，特别是化合物Iw（4-CF 3 -苯基醚）对Mythimna separata、Helicoverpa armigera和Pyrausta nubilalis的死亡率高于依托恶唑。鉴于杀螨活性高、成本相对较低，Ic作为杀螨剂值得进一步研究。然后研究了用于大规模合成Ic的替代合成路线。

  DOI：

  10.1021/acs.jafc.2c04628
• 作为产物：
  描述：

  丙醇 、 1-(2-氯乙基)-4-(氯甲基)苯 在 sodium hydroxide 、 对苯二酚 作用下， 生成 (4-Vinyl-benzyl)-propyl-ether
  参考文献：
  名称：

  The Preparation and Polymerization of p-Vinylbenzyl Ethers

  摘要：

  DOI：

  10.1021/jo01054a070

文献信息

• ORGANIC ELECTRONIC MATERIAL, POLYMERIZATION INITIATOR AND THERMAL POLYMERIZATION INITIATOR, INK COMPOSITION, ORGANIC THIN FILM AND PRODUCTION METHOD FOR SAME, ORGANIC ELECTRONIC ELEMENT, ORGANIC ELECTROLUMINESCENT ELEMENT, LIGHTING DEVICE, DISPLAY ELEMENT, AND DISPLAY DEVICE
  申请人：Ishitsuka Kenichi

  公开号：US20130037753A1

  公开（公告）日：2013-02-14

  Disclosed is an organic electronic material comprising charge transporting compounds and ionic compounds having electron-accepting properties and high solubility in a solvent. The organic electronic material is characterized by comprising charge transporting compounds and ionic compounds, and in that at least one of the ionic compounds is any one kind of compounds represented by general formulas (1b)-(3b). (In the formulas Y 1 -Y 6 each independently represent a divalent linking group, R 1 -R 6 each independently represent an electron-attracting organic substituent (these structures can further have substituents and hetero-atoms, and R 1 , R 2 and R 3 , or, R 4 -R 6 can respectively combine and become a ring shape or a polymer shape) and L + represents a monovalent cation.)

  本文揭示了一种有机电子材料，包括具有电荷传输化合物和具有接受电子性质且在溶剂中具有高溶解度的离子化合物。该有机电子材料的特点在于包括电荷传输化合物和离子化合物，并且至少其中一个离子化合物是由通用式（1b）-（3b）表示的化合物中的任意一种。（在式中，Y1-Y6分别表示二价连接基团，R1-R6分别表示吸引电子的有机取代基（这些结构可以进一步具有取代基和杂原子，且R1、R2和R3，或者R4-R6可以分别结合形成环状或聚合物形状），L+表示一价阳离子。）
• Hydrogenated modified polymer, process for producing the same and composition containing the same
  申请人：JSR Corporation

  公开号：US20030100683A1

  公开（公告）日：2003-05-29

  An objective of the present invention is to provide a hydrogenated modified polymer which can afford a molded body excellent in improvement in the balance among the impact resistance, the strength, the adherability and as the appearance, and a process for producing the same as well as a composition containing the same. Another objective is to provide a composition which can afford a molded body excellent in the balance among the flame retardancy, the tensile strength, the tensile extension, the heat resistance, the characteristic at low temperature, the insulation property, the pliability and the like. The hydrogenated modified polymer of the invention is a hydrogenated polymer of a modified conjugated diene-based polymer obtained by reacting an alkoxysilane compound to a polymer which is polymerized a conjugated diene or a conjugated diene and another monomer using an organic alkali metal compound as a polymerization initiator in an inert organic solvent such as cyclohexane and the like. The hydrogenated modified polymer composition of the invention contains the above-mentioned hydrogenated modified polymer and at least one selected from the group consisting of nonpolar polymer, polar polymer and filler.

  本发明的目标是提供一种氢化改性聚合物，该聚合物能够提供在冲击抗性、强度、附着性和外观之间平衡改善的模塑体，以及生产该聚合物的方法和包含该聚合物的组合物。另一个目标是提供一种组合物，该组合物能够提供在阻燃性、拉伸强度、拉伸延伸、耐热性、低温特性、绝缘性、可塑性等方面平衡改善的模塑体。本发明的氢化改性聚合物是一种氢化的改性共轭二烯基聚合物，通过在惰性有机溶剂如环己烷等中使用有机金属碱作为聚合引发剂，将烯丙基二烯或烯丙基二烯和另一种单体聚合而成的聚合物中反应烷氧基硅烷化合物而得到。本发明的氢化改性聚合物组合物包含上述氢化改性聚合物和至少选自非极性聚合物、极性聚合物和填料的一种。
• Cellulose ester film, cellulose ester dope, protective film of polarizing plate and polarizing plate
  申请人：Konica Corporation.

  公开号：US20020102369A1

  公开（公告）日：2002-08-01

  Disclosed is a cellulose ester film comprising a polymer prepared by polymerizing at least one ethylenically unsaturated monomer selected from vinyl esters, vinyl esters having a functional group, acrylic esters, and acrylic esters having a functional group, wherein the polymer has a weight average molecular weight of not more than 5,000.

  本发明公开了一种纤维素酯膜，其包括通过聚合至少一种乙烯基不饱和单体而制备的聚合物，所述乙烯基不饱和单体包括乙烯酸酯、具有功能基的乙烯酸酯、丙烯酸酯和具有功能基的丙烯酸酯，其中所述聚合物的重均分子量不超过5,000。
• POLYMER-SUPPORTED METAL COMPLEX CATALYST
  申请人：Hashimoto Shunichi

  公开号：US20090227743A1

  公开（公告）日：2009-09-10

  The present invention relates to a polymer-supported rhodium (II) catalyst and its application, which includes addition reaction to carbon-carbon multiple bond in α-diazocarbonyl compounds, insertion reaction to C—H and X—H (X═N, O, S, Se, Si and the like) bonds, or rearrangement and additional cyclization reaction thereof A novel insoluble polymer-supported rhodium (II) complex was prepared through a ligand exchange reaction between an insoluble polymer and a rhodium (II) carboxylato complex, wherein the insoluble polymer was prepared by a copolymerization reaction of (i) a styrene derivative with substituted carboxylic acid, (ii) a stylene, and (iii) a linear alkane with both ends substituted by vinylbenzyloxy groups, Namely, a polymer-supported metal complex catalyst having the following chemical formula 1: wherein M 1 and M 2 are rhodium, and the like; and X is an oxygen atom, etc; and R 4 is an alkyl group, and the like; and k is 1 to 15%, m is 1 to 5% relative to k+l+m, and l is the remainder; and n is 4 and others; and R 1 is alkyl-2-(4′-alkyloxy phthalimido methyl), etc, R 2 is phenyl, etc; R 3 is 4,4′-(1,3-propyrene-1,3-dioxymethyl)phenyl, etc.

  本发明涉及一种聚合物支撑的二价铑催化剂及其应用，包括对α-重氮基化合物中的碳-碳多键进行加成反应，对C-H和X-H（其中X = N，O，S，Se，Si等）键进行插入反应，或对其进行重排和附加环化反应。通过不溶性聚合物与二价铑羧酸酯配合物之间的配体交换反应制备了一种新型不溶性聚合物支撑的铑（II）配合物，其中不溶性聚合物是由（i）一种苯乙烯衍生物与取代羧酸、（ii）一种苯乙烯和（iii）两端取代为乙烯基苯甲氧基基团的线性烷烃进行共聚反应制备的。即，具有以下化学式1的聚合物支撑金属配合物催化剂：其中M1和M2是铑等；X是氧原子等；R4是烷基等；k相对于k+l+m为1至15％，m为1至5％，l为余数；n为4等；R1是烷基-2-（4'-烷氧基邻苯二酰亚甲基）等，R2是苯基等；R3是4,4'-（1,3-丙烯-1,3-二氧甲基）苯基等。
• Organic Electronic Material, Ink Composition Containing Same, and Organic Thin Film, Organic Electronic Element, Organic Electroluminescent Element, Lighting Device, and Display Device Formed Therewith
  申请人：Funyuu Shigeaki

  公开号：US20120074360A1

  公开（公告）日：2012-03-29

  Provided are: an organic electronic material which can be easily multilayered and that can be used in substrates, such as resin, that cannot be processed at high temperatures; an ink composition containing the same; an organic thin film formed using said organic electronic material or said ink composition; and an organic electronic element and an organic EL element that are formed using said organic thin film and that have a superior luminous efficacy and emission lifespan than conventional elements. Specifically, provided are: an organic electronic material that is characterized by containing an oligomer or a polymer having a structure that branches into three or more directions and has at least one polymerizable substituent; an ink composition containing said organic electronic material; and an organic thin film prepared using the aforementioned organic electronic material. Further, provided are an organic electronic element and an organic electroluminescent element containing said organic thin film.

  提供了以下内容：一种有机电子材料，可以轻松地多层堆叠，并可用于无法在高温下加工的基板，例如树脂；包含相同材料的墨水组合物；使用该有机电子材料或该墨水组合物形成的有机薄膜；以及使用该有机薄膜形成的有机电子元件和有机EL元件，其具有比传统元件更优异的发光效率和发射寿命。具体而言，提供了一种有机电子材料，其特征在于包含具有分支结构且向三个或更多方向分支的寡聚物或聚合物，并具有至少一个可聚合取代基；包含该有机电子材料的墨水组合物；以及使用上述有机电子材料制备的有机薄膜。此外，还提供了包含该有机薄膜的有机电子元件和有机电致发光元件。