2,4-di(2-aminopyridine)-6-methylpyrimidine | 848189-14-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪类
• 英文名称: 2,4-di(2-aminopyridine)-6-methylpyrimidine
• 英文别名: 6-methyl-2-N,4-N-dipyridin-2-ylpyrimidine-2,4-diamine
• CAS: 848189-14-0
• 化学式: C₁₅H₁₄N₆
• 分子量: 278.316
• InChiKey: VFHHGIOCMPVGOY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  21
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  75.6
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  2,4-di(2-aminopyridine)-6-methylpyrimidine 、 copper(II) acetate monohydrate 以 甲醇 为溶剂， 以51%的产率得到[Cu(dapmp)(OAc)2]*H2O
  参考文献：
  名称：

  Synthesis, characterization and crystal structures of 2,4-di(2-aminopyridine)-6-methypyrimidine (dapmp), [Cu(dapmp)Cl2] and [Cu(dapmp)(CH3COO)2]·H2O

  摘要：

  The new ligand dapmp (1) has been synthesized and the reactions of CuCl2 . 2H(2)O and Cu(CH3COO)(2) . H2O with the new ligand in methanol afforded two crystalline polymorphic forms: [Cu(dapmp)Cl-2] (2) and [Cu(dapmp)(CH3COO)(2)] . H2O (3), where dapmp = 2,4-di(2-aminopyridine)-6-methylpyrimidine. Single crystal X-ray diffraction showed that (1) and (2) are each connected by hydrogen bonding to form a one-dimensional supermolecular compound and (3) is connected by hydrogen bonding to form a three-dimensional supermolecular compound. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2004.11.013