[Ni(5,6,12,13-Me4-[14]-4,11-dieneN4)]3[Cr(NCS)6]2 | 464191-13-7

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: [Ni(5,6,12,13-Me4-[14]-4,11-dieneN4)]3[Cr(NCS)6]2
• CAS: 464191-13-7
• 化学式: C₅₄H₈₄Cr₂N₂₄Ni₃S₁₂
• 分子量: 1734.28
• InChiKey: RHDVUIVIFDHIQO-ACOOGLNXSA-N

反应信息

• 作为产物：
  描述：

  [Ni(5,6,12,13-Me4-[14]-4,11-dieneN4)](ClO4)2 、 以 乙腈 为溶剂， 生成 [Ni(5,6,12,13-Me4-[14]-4,11-dieneN4)]3[Cr(NCS)6]2
  参考文献：
  名称：

  Heteronuclear thiocyanate-bridged compounds of the type (NiL)3[M(NCS)6]2 (M=Fe(III), Cr(III); L=5,6,12,13-Me4-[14]-4,11-dieneN4)

  摘要：

  The complexes of the general formula (NiL)(2)[M(NCS)(6)](2) (where L = 5,6,12,13-Me-4-[14]-4,11-diene-N-4, M = Fe(III) (1), Cr(III) (2)) were obtained and their magnetic and spectroscopic properties characterized. For the compound (NiL)(3)[Fe(NCS)(6)](2), the crystal structure was determined and X-ray analysis showed that it forms a linear pentanuclear compound NiFeNiFeNi in which the peripheral nickel(II) ions are five-co-ordinate. Magnetic studies for both compounds showed the existence of structural differences between them. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(02)00879-4