[Co(II)(2-(1H-benzimidazol-2-yl)phenolato)2]*(2-(1H-benzimidazol-2-yl)phenol)*(methanol) | 1290113-06-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并咪唑类
• 英文名称: [Co(II)(2-(1H-benzimidazol-2-yl)phenolato)2]*(2-(1H-benzimidazol-2-yl)phenol)*(methanol)
• CAS: 1290113-06-2
• 化学式: CH₄O*C₁₃H₁₀N₂O*C₂₆H₁₈CoN₄O₂
• 分子量: 719.725
• InChiKey: QFSOYGXQQYAUNL-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  甲醇 、 2-(2-羟基苯基)-1H-苯并咪唑 、 cobalt(II) perchlorate hexahydrate 以 甲醇 、 水 为溶剂， 以53%的产率得到[Co(II)(2-(1H-benzimidazol-2-yl)phenolato)2]*(2-(1H-benzimidazol-2-yl)phenol)*(methanol)
  参考文献：
  名称：

  Structure and magnetism of Co(II) complexes with bidentate heterocyclic ligand Hsalbim derived from benzimidazole

  摘要：

  Two mononuclear Co(II) complexes based upon 2-(1H-benzimidazol-2-yl)phenol, abbreviation Hsalbim ligand, have been prepared and studied. The structure of Hsalbim and [Co(salbim)(2)] have been confirmed by X-ray structure analysis. The second cobalt(II) complex matches the formula [Co(salbim)(2)]center dot(Hsalbim)center dot MeOH assuming a co-crystallization of one neutral ligand. The electronic spectra are consistent with the tetrahedral pattern. Magnetic susceptibility measurements down to T = 2 K along with the magnetization data until B = 7 T show that the Co(II) complexes are high-spin with a considerable zero-field splitting of the B-4(1)(D-2d) term: D/hc = 67 and 55 cm(-1), respectively. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2011.01.021