[Cu(η2-S2CNMe2)2][ClO4] | 306767-83-9

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机含氧阴离子化合物
• 英文名称: [Cu(η2-S2CNMe2)2][ClO4]
• CAS: 306767-83-9
• 化学式: C₆H₁₂CuN₂S₄*ClO₄
• 分子量: 403.435
• InChiKey: PKBVIAYNQSZGHL-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  橡胶促进剂 CDD 、 copper(II) perchlorate hexahydrate 生成 [Cu(η2-S2CNMe2)2][ClO4]
  参考文献：
  名称：

  Crystal structures of copper(III) dithiocarbamate complexes [Cu(η2-S2CNMe2)2][ClO4] and [Cu(η2-S2CNEt2)2][FeCl4] with and without anion–cation interactions

  摘要：

  Copper(III) dithiocarbamate complexes [Cu(eta(2)-S2CNMe2)(2)][ClO4] and [Cu(eta(2)-S2CNEt2)(2)][FeCl4] have been characterised crystallographically. Both contain square-planar Cu(III) centres which attain an overall distorted octahedral coordination environment via long-range intermolecular interactions. In [Cu(eta(2)-S2CNEt2)(2)][FeCl4]. anions and cations do not interact and Cu(III) centres form an infinite chain held together by weak copper-sulfur interactions. In [Cu(eta(2)-S2CNMe2)(2)][ClO4], perchlorate anions interact weakly with the Cu(III) centre [Cu-O 2.753(3) Angstrom] which attains overall six coordination via a Cu-S interaction with a second copper-dithiocarbamate-perchlorate unit. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(00)00172-9

文献信息

• Sharma; Kumar, Satish; Chauhan, Chetan, Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 2007, vol. 46, # 7, p. 1121 - 1124
  作者：Sharma、Kumar, Satish、Chauhan, Chetan、Gupta, Atul

  DOI：——

  日期：——