1,4-diisopropyl-7-(2-methylpyridyl)-1,4,7-triazacyclononane | 176483-81-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 1,4-diisopropyl-7-(2-methylpyridyl)-1,4,7-triazacyclononane
• 英文别名: 1-(2-pyridylmethyl)-4,7-diisopropyl-1,4,7-triazacyclononane；(py)(iPr)2[9]aneN3；1,4-Di(propan-2-yl)-7-(pyridin-2-ylmethyl)-1,4,7-triazonane
• CAS: 176483-81-1
• 化学式: C₁₈H₃₂N₄
• 分子量: 304.479
• InChiKey: LVEWGAHCSYYSKJ-UHFFFAOYSA-N

物化性质

• 沸点：
  398.2±32.0 °C(Predicted)
• 密度：
  0.986±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  22
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.72
• 拓扑面积：
  22.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1,4-diisopropyl-7-(2-methylpyridyl)-1,4,7-triazacyclononane 以 四氢呋喃 、 乙腈 为溶剂， 生成 [trans-1,2-dicopper(I)(η4-1,4-diisopropyl-7-(2-pyridyl)-1,4,7-triazacyclononane)2](O3SCF3)2
  参考文献：
  名称：

  Dioxygen Activation by a Copper(I) Complex of a New Tetradentate Tripodal Ligand:  Mechanistic Insights into Peroxodicopper Core Reactivity

  摘要：

  DOI：

  10.1021/ja962344o
• 作为产物：
  描述：

  2-溴丙烷 、 1-(2-methylpyridyl)-1,4,7-triazacyclononane 在 sodium carbonate 作用下， 以 乙腈 为溶剂， 生成 1,4-diisopropyl-7-(2-methylpyridyl)-1,4,7-triazacyclononane
  参考文献：
  名称：

  Pendant arm N-monofunctionalised 1,4,7-triazacyclononane complexes of Fe(ii) and Ru(ii)

  摘要：

  研究了一系列铁(II)和钌(II)的三氮杂环壬烷和垂臂三氮杂环壬烷衍生物。这项工作的目的是：(i) 使用 N-单官能化的 1,4,7-三氮杂环壬烷大环稳定活性二氯化铁（II）片段；(ii) 研究悬臂基团大环对创造不同的钌（II）环境的影响。

  DOI：

  10.1039/b205344f

文献信息

• New N-monofunctionalised 1,4,7-triazacyclononane complexes of iron
  作者：Patrick C. McGowan、Claire N. Temple

  DOI：10.1016/j.ica.2009.02.015

  日期：2009.7

  A series of 1,4,7-triazacyclononane derivatives of Fe(II) been investigated where changing the functionality of a pendant group has created different Fe(II) coordination environments. New examples of triazacyclononane supported iron dibromide complexes are presented as well as an iron complex bearing a novel 1,4,7-triazacyclononane containing a thiophene pendant-arm. (C) 2009 Elsevier B. V. All rights reserved.
• Mono- versus bidentate coordination of the NONOate [Et2N(N2O2)]- to copper(II) complexes of tetradentate ligands
  作者：Jamie L. Schneider、Jason A. Halfen、Victor G. Young, Jr.、William B. Tolman

  DOI：10.1039/a800561c

  日期：——

  Copper(II) complexes of [Et2N(N2O2)](-) with tetradentate, tripodal ligands composed of 1,4,7-triazacyclononanes with pyridine (L-Py), amide (L-HAmH) Or phenolate (L-R2, R = Me, or Bu-t phenolate substituents) groups as the fourth donor were prepared and characterized by spectroscopic and X-ray crystallographic methods. Bidentate O,O-coordination of [Et2N(N2O2)](-) was observed in the complexes supported by L-Py and L-HAmH, but the stronger phenolate donor in L-R2 induced novel monodentate coordination via the terminal oxygen atom, defined by X-ray crystallography for R = Bu-t. Comparison of the bonding parameters of [Et2N(N2O2)](-) when bound bidentate vel sus when bound monodentate revealed subtle but significant differences in the N-O distances. The amount and rate of nitric oxide (NO) release from the compounds was measured using a chemiluminescence detection method. Despite the differences in [Et2N(N2O2)](-) structural parameters resulting from the divergent coordination modes, insignificant variation of the rates of NO release therefrom were found.
• Titanium <i>tert</i>-Butyl- and Trimethylsilyl-imido Complexes with Monopendant Arm Triazacyclononane Ligands
  作者：Jonathan D. Gardner、David A. Robson、Leigh H. Rees、Philip Mountford

  DOI：10.1021/ic0009728

  日期：2001.2.1
• NEAR INFRARED RAY ABSORBENT COMPOSITION, NEAR INFRARED RAY CUT FILTER, SOLID IMAGE PICKUP ELEMENT, AND CAMERA MODULE
  申请人：FUJIFILM Corporation

  公开号：US20170227690A1

  公开（公告）日：2017-08-10

  Provided are a near infrared ray absorbent composition which can form a cured film having excellent near infrared ray shielding properties, a near infrared ray cut filter, a manufacturing method of a near infrared ray cut filter, a solid image pickup element, and a camera module. The near infrared ray absorbent composition includes a copper complex that is other than a copper phthalocyanine complex and has a maximum absorption wavelength in a wavelength range of 700 to 1,200 nm and in which a molar light absorption coefficient at the maximum absorption wavelength is greater than or equal to 100 (L/mol·cm).
• NEAR INFRARED ABSORBING COMPOSITION, NEAR INFRARED CUT FILTER, METHOD OF MANUFACTURING NEAR INFRARED CUT FILTER, DEVICE, METHOD OF MANUFACTURING COPPER-CONTAINING POLYMER, AND COPPER-CONTAINING POLYMER
  申请人：FUJIFILM Corporation

  公开号：US20180094086A1

  公开（公告）日：2018-04-05

  The near infrared absorbing composition includes: a copper-containing polymer having a copper complex site at a polymer side chain; and a solvent, in which the copper complex site includes a site multidentate-coordinated to a copper atom and at least one selected from the group consisting of a site monodentate-coordinated to a copper atom and a counter ion to a copper complex skeleton, and a polymer main chain and a copper atom at the copper complex site are bonded to each other through the site monodentate-coordinated to a copper atom or the counter ion.