benzyl β-D-glucopyranosyl-(1->3)-β-D-glucopyranosyl-(1->3)-β-D-glucopyranosyl-(1->3)-β-D-glucopyranosyl-(1->3)-β-D-glucopyranosyl-(1->3)-β-D-mannopyranoside | 1206893-53-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: benzyl β-D-glucopyranosyl-(1->3)-β-D-glucopyranosyl-(1->3)-β-D-glucopyranosyl-(1->3)-β-D-glucopyranosyl-(1->3)-β-D-glucopyranosyl-(1->3)-β-D-mannopyranoside
• CAS: 1206893-53-9
• 化学式: C₄₃H₆₈O₃₁
• 分子量: 1080.99
• InChiKey: ARBQGVOJWJZJKK-RQVJQEKVSA-N

反应信息

• 作为反应物：
  描述：

  benzyl β-D-glucopyranosyl-(1->3)-β-D-glucopyranosyl-(1->3)-β-D-glucopyranosyl-(1->3)-β-D-glucopyranosyl-(1->3)-β-D-glucopyranosyl-(1->3)-β-D-mannopyranoside 在 氢气 、 palladium diacetate 作用下， 以 甲醇 为溶剂， 反应 168.0h， 以100%的产率得到β-D-glucopyranosyl-(1->3)-β-D-glucopyranosyl-(1->3)-β-D-glucopyranosyl-(1->3)-β-D-glucopyranosyl-(1->3)-β-D-glucopyranosyl-(1->3)-D-mannopyranoside
  参考文献：
  名称：

  New oligo-β-(1,3)-glucan derivatives as immunostimulating agents

  摘要：

  Oligo-beta-(1,3)-glucans were chemically modified in order to introduce a structural variation specifically on the reducing end of the oligomers. The impact of well defined structural modulations was further studied on cancer cells and murin models to evaluate their cytotoxicity and immunostimulating potential.

  DOI：

  10.1016/j.bmc.2009.10.053
• 作为产物：
  描述：

  benzyl 2,3,4,6-tetra-O-benzoyl-β-D-glucopyranosyl-(1->3)-2,4,6-tri-O-benzoyl-β-D-glucopyranosyl-(1->3)-2,4,6-tri-O-benzoyl-β-D-glucopyranosyl-(1->3)-2,4,6-tri-O-benzoyl-β-D-glucopyranosyl-(1->3)-2,4,6-tri-O-benzoyl-β-D-glucopyranosyl-(1->3)-4,6-di-O-benzoyl-β-D-mannopyranoside 在 sodium methylate 作用下， 以 甲醇 、 二氯甲烷 为溶剂， 反应 6.0h， 以96%的产率得到benzyl β-D-glucopyranosyl-(1->3)-β-D-glucopyranosyl-(1->3)-β-D-glucopyranosyl-(1->3)-β-D-glucopyranosyl-(1->3)-β-D-glucopyranosyl-(1->3)-β-D-mannopyranoside
  参考文献：
  名称：

  New oligo-β-(1,3)-glucan derivatives as immunostimulating agents

  摘要：

  Oligo-beta-(1,3)-glucans were chemically modified in order to introduce a structural variation specifically on the reducing end of the oligomers. The impact of well defined structural modulations was further studied on cancer cells and murin models to evaluate their cytotoxicity and immunostimulating potential.

  DOI：

  10.1016/j.bmc.2009.10.053