bis[5-(3-oxyphenyl)-2,2,12,18-tetrabutyl-3,7,13,17-tetramethylporphyrinatozinc(II)]-3,6,9-trioxyundecane-1,11 | 1237706-71-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: bis[5-(3-oxyphenyl)-2,2,12,18-tetrabutyl-3,7,13,17-tetramethylporphyrinatozinc(II)]-3,6,9-trioxyundecane-1,11
• 英文别名: 3,6,9-trioxaundecane-1,11-bis[2,8,12,18-tetrabutyl-3,7,13,17-tetrametyl-5-(3-oxyphenyl)porphyrinatozinc(II)]
• CAS: 1237706-71-6
• 化学式: C₁₀₀H₁₂₆N₈O₅Zn₂
• 分子量: 1650.93
• InChiKey: CVRALUUOJRGTDV-LDOOXXCTSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  三乙烯二胺 、 bis[5-(3-oxyphenyl)-2,2,12,18-tetrabutyl-3,7,13,17-tetramethylporphyrinatozinc(II)]-3,6,9-trioxyundecane-1,11 以 toluene 、 methanol 为溶剂， 生成 (DABCO)2(3.6.9-trioxaundecane-1,11-bis[2,8,12,18-tetrabutyl-3,7,13,17-tetrametyl-5-(3-oxyphenyl)porphyrinatozinc(II)])
  参考文献：
  名称：

  Complexing ability of dimeric zinc octaalkylporphyrinates with a poly(ethyleneoxy) bridge toward 1,4-diazabicyclo[2.2.2]octane and 1,4-diazine

  摘要：

  The formation of "guest-host" complexes from dimeric zinc octaalkylporphyrinates with a poly(ethyleneoxy) bridge and various bidentate ligands containing two N atoms was studied by spectrophotometric titration and H-1 NMR spectroscopy in toluene-methanol (5: 1). The reactions of dimeric porphyrinates with 1,4-diazabicyclo[2.2.2]octane and 1,4-diazine gave 1: 1 or 1: 2 complexes, depending on the molar ratio of metal porphyrin and the ligand. The stability constants of the complexes obtained and the concentration ranges for their formation were determined.

  DOI：

  10.1134/s1070328410040111
• 作为产物：
  描述：

  zinc diacetate 、 1,11-bis[3-(2,8,12,18-tetrabutyl-3,7,13,17-tetramethylporphyrin-5-yl)phenoxy]-3,6,9-trioxaundecane 以 ethanol 为溶剂， 生成 bis[5-(3-oxyphenyl)-2,2,12,18-tetrabutyl-3,7,13,17-tetramethylporphyrinatozinc(II)]-3,6,9-trioxyundecane-1,11
  参考文献：
  名称：

  Complexation and basic properties of polyethylene oxide-substituted porphyrins

  摘要：

  Basic properties of bis[5-(3-oxyphenyl)-2,8,12,18-tetrabutyl-3,7,13,17-tetramethylporphyrinyl]-3,6,9-trioxyundecane-1,11 and bis[5-(3-oxyphenyl)-2,8,12,18-tetrabutyl-3,7,13,17-tetramethylporphyrinyl]-3,6,9,12-tetraoxytetradecane-1,14 were studied spectrophotometrically in an ethanol-sulfuric acid system; the influence of the basicity of the inner cycle nitrogen atom on the complexation properties of these polyethylene oxide-substituted porphyrins towards zinc cation in ethanol was considered.

  DOI：

  10.1134/s1070328409110104