2-propyl-benzyl chloride | 103323-66-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-propyl-benzyl chloride
• 英文别名: 2-Propyl-benzylchlorid；1-(Chloromethyl)-2-propylbenzene
• CAS: 103323-66-6
• 化学式: C₁₀H₁₃Cl
• mdl: MFCD19235162
• 分子量: 168.666
• InChiKey: TVFGUBMFGNNSHG-UHFFFAOYSA-N

物化性质

• 沸点：
  230.0±9.0 °C(Predicted)
• 密度：
  1.013±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  11
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  (2-丙基苯基)甲醇 在 氯化亚砜 、 N,N-二甲基苯胺 作用下， 生成 2-propyl-benzyl chloride
  参考文献：
  名称：

  Haddow et al., Philosophical Transactions of the Royal Society of London, 1948, vol. 241, p. 147,188

  摘要：

  DOI：

文献信息

• TROPANE DERIVATIVES USEFUL AS PESTICIDES
  申请人：Selles Patrice

  公开号：US20100331348A1

  公开（公告）日：2010-12-30

  Compounds of formula (I) wherein the substituents have the meanings assigned to them in claim 1, are useful as pesticides.

  式(I)中的化合物，其中取代基具有在权利要求书1中分配给它们的含义，可用作杀虫剂。
• Textile conditioning compositions with low content of cationic guar gum
  申请人：THE PROCTER & GAMBLE COMPANY

  公开号：EP0002085A2

  公开（公告）日：1979-05-30

  A textile conditioning composition, especially a liquid composition, intended for use in the final rinse after a washing operation comprises a cationic surfactant, a substantially water insoluble nonionic textile softening agent and a small amount of a polymeric cationic salt, the weight ratio of cationic components to nonionic softener being less than 10:1. Preferred cationic surfactants are the substantially water-insoluble quaternary ammonium fabric softeners and preferred nonionic softening agents are the fatty acid esters of glycerol or sorbitan: Especially useful polymeric materials include the cationic galactomannan gums. especially guar gum.

  一种纺织品护理组合物，特别是一种液体组合物，用于洗涤操作后的最后冲洗，由阳离子表面活性剂、基本不溶于水的非离子织物柔软剂和少量聚合物阳离子盐组成，阳离子成分与非离子柔软剂的重量比小于 10:1。首选的阳离子表面活性剂是基本上不溶于水的季铵织物柔软剂，首选的非离子柔软剂是甘油或山梨醇的脂肪酸酯：特别有用的聚合物材料包括阳离子半乳甘露聚糖胶，尤其是瓜尔豆胶。
• Method for producing diarylmethanes
  申请人：KUREHA KAGAKU KOGYO KABUSHIKI KAISHA

  公开号：EP0428081A1

  公开（公告）日：1991-05-22

  The present invention relates to a method for producing diarylmethanes represented by the following formula (III) wherein R¹ to R³ each stand for a hydrogen atom or an alkyl group having 1 to 3 carbon atoms. This method comprises the reaction of a benzyl chloride represented by the following general formula (I) with benzene or an alkylbenzene represented by the following general formula (II): wherein R¹ to R³ have the same meanings as defined above. and is characterized in that the catalyst used is an HY or HL type zeolite having a SiO₂/Al₂O₃ molar ratio of 4 -­10 and an alkali metal content of 5% by weight or less, calculated as an alkali metal oxide, or a zeolite obtained by the exchange of said NY or HL type zeolite with cations of a di- or tri-valent metal.

  本发明涉及一种生产下式（III）所代表的二芳基甲烷的方法 其中 R¹ 至 R³ 分别代表氢原子或具有 1 至 3 个碳原子的烷基。该方法包括如下通式 (I) 所代表的苄基氯与如下通式 (II) 所代表的苯或烷基苯反应： 其中 R¹ 至 R³ 的含义与上述定义相同。其特征在于，所用催化剂是一种 HY 或 HL 型沸石，其 SiO₂/Al₂O₃ 摩尔比为 4 -10，碱金属含量为 5%（重量）或以下（以碱金属氧化物计算），或者是一种通过将所述 NY 或 HL 型沸石与二价或三价金属阳离子交换而得到的沸石。
• Process for preparing 1-bromoalkylbenzene derivatives and intermediates thereof
  申请人：SUMITOMO CHEMICAL COMPANY LIMITED

  公开号：EP0637580A1

  公开（公告）日：1995-02-08

  A 1-bromoalkylbenzene derivative is prepared by reacting a phenylalkene derivative with hydrogen bromide in the presence of a non-polar solvent. The phenylalkene derivative is prepared by reacting an alkenyl halide with metal magnesium to form a Grignard reagent, and then reacting the Grignard reagent with a benzyl halide derivative. An allyl Grignard reagent is prepared by reacting continuously an allyl halide derivative with metal magnesium in an organic solvent, in which the allyl halide derivative and metal magnesium are continuously added to the reaction system and the allyl Grignard reagent formed is continuously removed from the reaction system. The processes provide the intended compounds in high yields, high selectivities and high purities.

  1-bromoalkylbenzene derivative is prepared by reacting a phenylalkene derivative with hydrogen bromide in the presence of a non-polar solvent.苯基烷烃衍生物的制备方法是先使烯基卤化物与金属镁反应生成格氏试剂，然后使格氏试剂与苄基卤化物衍生物反应。烯丙基格氏试剂是通过烯丙基卤化物衍生物与金属镁在有机溶剂中连续反应制备的，其中烯丙基卤化物衍生物和金属镁被连续加入反应体系，形成的烯丙基格氏试剂被连续从反应体系中移除。这些工艺可提供高产率、高选择性和高纯度的预期化合物。
• A PROCESS FOR THE PREPARATION OF CYCLOBUTENE-SUBSTITUTED AROMATIC HYDROCARBONS
  申请人：THE DOW CHEMICAL COMPANY

  公开号：EP0182872A1

  公开（公告）日：1986-06-04