bis(diethyldithiocarbamato)piperidinezinc(II), adduct with morpholine | 352552-52-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 恶嗪烷类
• 英文名称: bis(diethyldithiocarbamato)piperidinezinc(II), adduct with morpholine
• CAS: 352552-52-4
• 化学式: C₄H₉NO*C₁₅H₃₁N₃S₄Zn
• 分子量: 534.207
• InChiKey: AJYQNXNSTHMQHH-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  吗啉 、 bis(diethyldithiocarbamato)piperidinezinc(II) 生成 bis(diethyldithiocarbamato)piperidinezinc(II), adduct with morpholine
  参考文献：
  名称：

  摘要：

  Crystal adducts of diethyldithiocarbamate complexes of zinc(II) and copper(II) with piperidine (Pip) were synthesized, and their solvated forms with the outer-sphere molecules of benzene, pyridine (Py), and morpholine (Mf) were obtained. Adducts with composition [M(Pip)(Edtc)(2)] . L (L = Py, Mf) were shown to he able, in principle, to give solvated isomers IM(L)(Edtc)(2)] . Pip with the Pip molecule arranged in the outer sphere. The composition, structure, and properties of the obtained adducts were studied by EPR, high-resolution solid-state C-13, N-15 NMR spectroscopy. Solvation of all three adducts with Pip, Mf, and Py was found to result in a substantial increase in the contribution of the trigonal-bipyramidal component to the geometry of a copper coordination pentahedron. In addition, for adducts with Mf and Py, a structural unification of two isomeric forms was observed at the molecular level to yield a qualitatively new (rather than intermediate) state. It was shown that in all solvated forms of the copper(II) adducts, the metal polyhedron is mainly a trigonal bipyramid, while the square-pyramidal contribution is insignificant. Results of(C-13, N-15) NMR studies revealed a structural inequivalence of the Edtc(-) ligands in the zinc adducts under investigation.

  DOI：

  10.1023/a:1009590026768