1-bromo-2,5-dihexyl-4-iodobenzene | 187275-61-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-bromo-2,5-dihexyl-4-iodobenzene
• 英文别名: Benzene, 1-bromo-2,5-dihexyl-4-iodo-
• CAS: 187275-61-2
• 化学式: C₁₈H₂₈BrI
• 分子量: 451.229
• InChiKey: XHYLGTRHJRAXFT-UHFFFAOYSA-N

物化性质

• 熔点：
  37-38 °C
• 沸点：
  433.7±33.0 °C(Predicted)
• 密度：
  1.386±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  9.2
• 重原子数：
  20
• 可旋转键数：
  10
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1-bromo-2,5-dihexyl-4-iodobenzene 在 bis-triphenylphosphine-palladium(II) chloride 、 sodium hydroxide 、 copper(l) iodide 、 正丁基锂 、 1,2-二碘乙烷 、 二乙胺 作用下， 以 四氢呋喃 、 甲醇 为溶剂， 反应 2.5h， 生成 2-[4-[2-(2,5-Dihexyl-4-iodophenyl)ethynyl]-2,5-dihexylphenyl]ethynyl-trimethylsilane
  参考文献：
  名称：

  Synthesis and Characterization of Monodisperse Oligo(phenyleneethynylene)s

  摘要：

  DOI：

  10.1021/jo970548x
• 作为产物：
  描述：

  2,5-双(己基)-1,4-二溴苯 在 正丁基锂 、 碘 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 反应 0.33h， 以75%的产率得到1-bromo-2,5-dihexyl-4-iodobenzene
  参考文献：
  名称：

  包含Vollhardt的环丁二烯配合物的共轭有机金属聚合物：聚集体和形态。

  摘要：

  有机金属聚合物是通过无环二炔复分解（ADIMET）或通过Pd催化的1,3-二乙炔基环丁二烯（环戊二烯基）钴与适当取代的二碘苯的偶联而制得的。通过Heck偶联获得的聚合物显示出20-60的聚合度（Pn）。ADIMET的单体通过[1,3-双（三甲基硅烷基乙炔基）-2,4-双（三甲基硅烷基）环丁二烯]（环戊二烯基）钴的Pd催化偶联至1-溴-2,5-二烷基-4-在KOH存在下，丙炔基苯的收率为40-48％。单体带有己基，乙基己基和（S）-3,7-二甲基辛基侧链。炔丙基化单体的聚合为有机金属聚合物提供了最多230个亚芳基-亚乙炔基单元的Pn。通过偏光显微镜，透射电子显微镜，圆二色性，差示扫描量热法和X射线衍射（XRD）。它们显示出向列型，溶致液晶相以及手性，由此可以推断在不良溶剂和固态下的聚集。这些有机金属聚合物中的层状或不规则蜂窝状形态可以通过电子显微镜检测。

  DOI：

  10.1002/1521-3765(20010105)7:1<117::aid-chem117>3.0.co;2-5

文献信息

• A Biphenyl Construction Kit for Modular Chemistry
  作者：Volker Hensel、A.-Dieter Schlüter

  DOI：10.1002/jlac.199719970205

  日期：1997.2

  The synthesis of a number of telechelic biphenyls with one of the functional groups, B(OH)2, TMS, Br and I, at each ring is presented. These biphenyls constitute a construction kit for modular chemistry using the Suzuki cross-coupling protocol.

  提出了在每个环上带有一个官能团B（OH）2，TMS，Br和I的许多遥螯联苯的合成。这些联苯构成了使用Suzuki交叉偶联方案进行模块化化学反应的构建试剂盒。
• Hole transport materials
  申请人：LG Chem, Ltd.

  公开号：US10439140B2

  公开（公告）日：2019-10-08

  There is provided a hole transport polymer having a carbazole group and an amino nitrogen having Formula I In the formula: Ar1, Ar2, and Ar4 are the same or different and are substituted or unsubstituted aryl groups or deuterated aryl groups; Ar3 is substituted or unsubstituted aryl groups or deuterated aryl groups; E is the same or different at each occurrence and is selected from the group consisting of H, D, halide, alkyl, aryl, siloxane, deuterated alkyl, deuterated aryl, deuterated siloxane, and a crosslinking group; R1-R2 are the same or different at each occurrence and are selected from the group consisting of D, F, CN, alkyl, fluoroalkyl, aryl, heteroaryl, amino, silyl, germyl, alkoxy, aryloxy, fluoroalkoxy, siloxane, siloxy, deuterated alkyl, deuterated partially-fluorinated alkyl, deuterated aryl, deuterated heteroaryl, deuterated amino, deuterated silyl, deuterated germyl, deuterated alkoxy, deuterated aryloxy, deuterated fluoroalkoxy, deuterated siloxane, deuterated siloxy, and crosslinking groups, wherein adjacent groups selected from R1 and R2 can be joined together to form a fused ring; a is an integer from 0-4; b is an integer from 0-3; and n is an integer greater than or equal to 1.

  提供了一种具有咔唑基团和氨基氮的空穴传输聚合物，其式为 I 式中Ar1、Ar2 和 Ar4 相同或不同，并且是取代或未取代的芳基或氚代芳基；Ar3 是取代或未取代的芳基或氚代芳基；E 在每次出现时相同或不同，并且选自由 H、D、卤化物、烷基、芳基、硅氧烷、氚代烷基、氚代芳基、氚代硅氧烷和交联基团组成的组；R1-R2 在每次出现时相同或不同，并且选自由 D、F、CN、烷基、氟烷基、芳基、杂芳基、氨基、硅基、芽基、烷氧基、芳氧基、氟烷氧基、硅氧烷、硅氧基、氚代烷基、氚代部分氟化烷基、氚代芳基、氚代杂芳基、氚代芳基、氚代硅氧烷和交联基团组成的组、氚代杂芳基、氚代氨基、氚代硅烷基、氚代胚芽基、氚代烷氧基、氚代芳氧基、氚代氟烷氧基、氚代硅氧烷、氚代硅氧基和交联基团，其中选自 R1 和 R2 的相邻基团可连接在一起形成融合环；a 是 0-4 的整数；b 是 0-3 的整数；n 是大于或等于 1 的整数。
• Acharya, Jiba Raj; Zhang, Huating; Li, Xian, Journal of the American Chemical Society, 2009, vol. 131, p. 880 - 881
  作者：Acharya, Jiba Raj、Zhang, Huating、Li, Xian、Nesterov, Evgueni E.

  DOI：——

  日期：——
• HOLE TRANSPORT MATERIALS
  申请人：E I DU PONT DE NEMOURS AND COMPANY

  公开号：US20170358750A1

  公开（公告）日：2017-12-14

  There is provided a hole transport polymer having a carbazole group and an amino nitrogen having Formula I In the formula: Ar 1 , Ar 2 , and Ar 4 are the same or different and are substituted or unsubstituted aryl groups or deuterated aryl groups; Ar 3 is substituted or unsubstituted aryl groups or deuterated aryl groups; E is the same or different at each occurrence and is selected from the group consisting of H, D, halide, alkyl, aryl, siloxane, deuterated alkyl, deuterated aryl, deuterated siloxane, and a crosslinking group; R 1 -R 2 are the same or different at each occurrence and are selected from the group consisting of D, F, CN, alkyl, fluoroalkyl, aryl, heteroaryl, amino, silyl, germyl, alkoxy, aryloxy, fluoroalkoxy, siloxane, siloxy, deuterated alkyl, deuterated partially-fluorinated alkyl, deuterated aryl, deuterated heteroaryl, deuterated amino, deuterated silyl, deuterated germyl, deuterated alkoxy, deuterated aryloxy, deuterated fluoroalkoxy, deuterated siloxane, deuterated siloxy, and crosslinking groups, wherein adjacent groups selected from R 1 and R 2 can be joined together to form a fused ring; a is an integer from 0-4; b is an integer from 0-3; and n is an integer greater than or equal to 1.
• Hole Transport Materials
  申请人：LG Chem, Ltd.

  公开号：US20190348607A1

  公开（公告）日：2019-11-14

  A hole transport copolymer having the following Formula III is disclosed herein: In some embodiments, A is a monomeric unit having Formula Ia or Formula IIa, B is a B is a monomeric unit having at least three points of attachment in the copolymer, E is the same or different at each occurrence and is selected from the group consisting of H, D, halide, alkyl, aryl, arylamino, siloxane, crosslinkable groups, deuterated alkyl, deuterated aryl, deuterated arylamino, deuterated siloxane, and deuterated crosslinkable groups, and x, y, and z are the same or different and are mole fractions, such that x+y+z=1, and x and y are non-zero.