| 1588866-18-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 1588866-18-5
• 化学式: CF₃O₃S*C₃₂H₃₆AgN₄O₄S₂
• 分子量: 861.733
• InChiKey: SWIPJIFMYHFHPU-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  N³-benzyl-N¹,N⁵-ditosyl-3-aza-1,5-pentanediamine 在 potassium carbonate 作用下， 以 1,2-二氯乙烷 、 乙腈 为溶剂， 反应 10.0h， 生成
  参考文献：
  名称：

  Mild Regiospecific Synthesis of 1-Alkoxy-isochromenes Catalyzed by Well-Defined [Silver(I)(Pyridine-Containing Ligand)] Complexes

  摘要：

  The synthesis of 3-substituted-1-alkoxyisochromenes starting from 2-alkynylbenzaldehydes and different alcohols is reported. The reaction is catalyzed by a silver(1) complex with an original macrocyclic pyridine-containing ligand. The approach is characterized by absolute regioselectivity, mild reaction conditions, good to excellent reaction yields, cleanness of the reaction, and reduced purification steps. The reaction mechanism was investigated by in-depth H-1 NMR experiments and an aimed "trapping" experiment.

  DOI：

  10.1021/jo5002559
• 作为试剂：
  描述：

  2-(4-hydroxybut-1-yn-1-yl)benzaldehyde 在 作用下， 以 甲苯 为溶剂， 反应 4.5h， 以50%的产率得到3,4-dihydro-1H-1,5-epoxybenzo[c]oxocine
  参考文献：
  名称：

  Mild Regiospecific Synthesis of 1-Alkoxy-isochromenes Catalyzed by Well-Defined [Silver(I)(Pyridine-Containing Ligand)] Complexes

  摘要：

  The synthesis of 3-substituted-1-alkoxyisochromenes starting from 2-alkynylbenzaldehydes and different alcohols is reported. The reaction is catalyzed by a silver(1) complex with an original macrocyclic pyridine-containing ligand. The approach is characterized by absolute regioselectivity, mild reaction conditions, good to excellent reaction yields, cleanness of the reaction, and reduced purification steps. The reaction mechanism was investigated by in-depth H-1 NMR experiments and an aimed "trapping" experiment.

  DOI：

  10.1021/jo5002559

文献信息

• Organometallic Reactivity of [Silver(I)­(Pyridine‐Containing Ligand)] Complexes Relevant to Catalysis
  作者：Tommaso Pedrazzini、Paolo Pirovano、Monica Dell'Acqua、Fabio Ragaini、Pasquale Illiano、Piero Macchi、Giorgio Abbiati、Alessandro Caselli

  DOI：10.1002/ejic.201500771

  日期：2015.10

  Silver(I) complexes of pyiridine-containing macrocyclic ligands (Pc-L) have already been demonstrated as active catalysts for some domino and multicomponent reactions. Here, we report new chiral [AgI(Pc-L*)] cationic complexes that have been synthesized and fully characterized, including structural determination by single-crystal X-ray diffraction. The complexes show a rich coordination chemistry,

  含吡啶的大环配体 (Pc-L) 的银 (I) 配合物已被证明是一些多米诺骨牌和多组分反应的活性催化剂。在这里，我们报告了新的手性 [AgI(Pc-L*)] 阳离子配合物，这些配合物已经合成并完全表征，包括通过单晶 X 射线衍射进行结构测定。这些配合物显示出丰富的配位化学，证明了银的 σ-亲（醇和腈配位）和 π-亲（炔配位）性质。已通过NMR光谱实验在溶液中观察到银上配体的萘基悬臂的η2配位模式。2D NMR 光谱显示存在由旋转过程产生的正交叉峰，旋转速率通过使用 2D 交换光谱 (EXSY) 测量。