[Ir(5-methyl-2-phenylpyridine(-1H))2(OH2)2](trifluoromethanesulfonate) | 1004784-72-8

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磺酸及其衍生物
• 英文名称: [Ir(5-methyl-2-phenylpyridine(-1H))2(OH2)2](trifluoromethanesulfonate)
• CAS: 1004784-72-8
• 化学式: CF₃O₃S*C₂₄H₂₄IrN₂O₂
• 分子量: 713.757
• InChiKey: VEKLIWNIRNPJOH-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Ir(5-methyl-2-phenylpyridine(-1H))2(OH2)2](trifluoromethanesulfonate) 、 benzo[4,5]benzo[4',5']imidazo[2',1':2,3][1,3]diazepino[6,7,1-jk]carbazole 以 甲醇 、 乙醇 为溶剂， 反应 20.0h， 生成
  参考文献：
  名称：

  ORGANIC ELECTROLUMINESCENT MATERIALS AND DEVICES

  摘要：

  本发明涉及化合物，可作为磷光电致发光器件的主体材料。本发明还包括新型金属配合物配体，产生的配合物可作为电致发光器件中的发射体。

  公开号：

  US20180315935A1
• 作为产物：
  描述：

  tetrakis-(5-methyl-2-phenylpyridine(-1H))-μ-(dichloro)-diiridium(III) 、 水 、 silver trifluoromethanesulfonate 以 乙醇 、 水 为溶剂， 以65%的产率得到[Ir(5-methyl-2-phenylpyridine(-1H))2(OH2)2](trifluoromethanesulfonate)
  参考文献：
  名称：

  Cyclometalated Iridium(III) Aquo Complexes:  Efficient and Tunable Catalysts for the Homogeneous Oxidation of Water

  摘要：

  A series of bis-phonylpyridine, bis-aquo iridium(III) complexes is herein shown to robustly and efficiently catalyze the oxidation of water to dioxygen in the presence of a sacrificial oxidant. Through substitution on the cyclometalating ligands of these complexes, it is shown that a broad range of oxidation potentials can be achieved within this class of catalyst. Parallel, dynamic monitoring of oxygen evolution, made possible by equipping reaction vessels with pressure-voltage transducers, facilitates correlation of these complexes' ionization potentials with their respective activity toward water oxidation. The importance of these catalysts lies in (A) their ability to oxidize water in a purely aqueous medium, (B) their simplicity of design, (C) their durability, and (D) the ease with which they can be tuned to accommodate the electrochemical needs of photosensitizers in hypothetical photochemical water oxidation and full artificial photosynthetic schemes.

  DOI：

  10.1021/ja074478f
• 作为试剂：
  描述：

  水 在 [Ir(5-methyl-2-phenylpyridine(-1H))2(OH2)2](trifluoromethanesulfonate) cerium(IV) ammonium nitrate 作用下， 以 水 为溶剂， 生成 氧气
  参考文献：
  名称：

  Cyclometalated Iridium(III) Aquo Complexes:  Efficient and Tunable Catalysts for the Homogeneous Oxidation of Water

  摘要：

  A series of bis-phonylpyridine, bis-aquo iridium(III) complexes is herein shown to robustly and efficiently catalyze the oxidation of water to dioxygen in the presence of a sacrificial oxidant. Through substitution on the cyclometalating ligands of these complexes, it is shown that a broad range of oxidation potentials can be achieved within this class of catalyst. Parallel, dynamic monitoring of oxygen evolution, made possible by equipping reaction vessels with pressure-voltage transducers, facilitates correlation of these complexes' ionization potentials with their respective activity toward water oxidation. The importance of these catalysts lies in (A) their ability to oxidize water in a purely aqueous medium, (B) their simplicity of design, (C) their durability, and (D) the ease with which they can be tuned to accommodate the electrochemical needs of photosensitizers in hypothetical photochemical water oxidation and full artificial photosynthetic schemes.

  DOI：

  10.1021/ja074478f