prop-1-ene;rhodium(3+);trimethylphosphane | 327029-90-3

• 分子结构分类: 有机化合物 - 有机磷化合物 - 有机膦及其衍生物
• 英文名称: prop-1-ene;rhodium(3+);trimethylphosphane
• CAS: 327029-90-3
• 化学式: C₁₅H₃₃P₂Rh
• 分子量: 378.28
• InChiKey: OEGURXVWANVECO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.73
• 重原子数：
  18
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  Rh(allyl)3 、 三甲基膦 以 甲苯 为溶剂， 以98.4%的产率得到prop-1-ene;rhodium(3+);trimethylphosphane
  参考文献：
  名称：

  Comparison of the Reactivity of M(allyl)₃ (M = Rh, Ir) with Donor Ligands

  摘要：

  Reactions of M(allyl)(3) [M = Rh, Ir] with a variety of donor ligands have been investigated. While both complexes are unreactive toward "hard" N- and O-donor ligands, "soft" ligands such as tolylisothiocyanate, tertiary phosphines, CO, and aryl isocyanides are readily added. Whereas ligand additions to Rh(allyl)(3) are often accompanied by reduction of the Rh(III) center, analogous reactions with Ir(allyl)(3) afford stable trivalent products containing sigma -allyl ligands. The molecular structures of several derivatives are presented, including Ir(sigma -allyl)(pi -allyl)(2)(PPh3), Ir(sigma -allyl)(2)(pi -allyl)(PMe3)(2), and Ir(sigma -allyl)(3)(C dropN-2,6-Me2C6H3)(3).

  DOI：

  10.1021/om000734k