| 215595-01-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 215595-01-0
• 化学式: C₂₀H₂₈N₂Pd
• 分子量: 402.876
• InChiKey: YYXTWMCQUYVVNT-TXBTUDEPSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-(((2,6-diisopropylphenyl)imino)methyl)pyridine 、 Pd(pyridine)2(methyl)2 以 甲苯 为溶剂， 以92%的产率得到
  参考文献：
  名称：

  Synthesis of dialkyl, diaryl and metallacyclic complexes of Ni and Pd containing pyridine, α-diimines and other nitrogen ligands

  摘要：

  The alkylation of NiCl(2)py(4) or PdCl(2)py(2) with organomagnesium or organolithium reagents affords dialkyl complexes cis-MR(2)py(2) (R = Me, CH2SiMe3, CH2Ph, CH2CMe2Ph, 2,4,6-C6H2Me3). The methyl and trimethylsilyl derivatives undergo ligand exchange reactions with chelating nitrogen ligands (alpha-diimines or 2-imidoylpyridines), yielding the corresponding dialkyl derivatives in good to excellent yields. A catalytic amount of PMe3 induces the transformation of the nickel complex Ni(CH2CMe2Ph)(2)py(2) into the metallacyclic derivative NiCH2CMe2-o-C6H4(py)(2). The latter, and the related palladacycle Pd(CH2CMe2-o-C6H4) (cod), also undergo facile ligand exchange reactions. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(03)00691-0