(mesityl)C((C4H2N)(C6H4)O)2B | 1162652-23-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: (mesityl)C((C4H2N)(C6H4)O)2B
• CAS: 1162652-23-4
• 化学式: C₃₀H₂₃BN₂O₂
• 分子量: 454.336
• InChiKey: LCCMHQJUDFUWBK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (mesityl)C((C4H2N)(C6H4)OH)((C4H3N)(C6H4)OH) 、 4-二甲基氨基苯硼酸 以 氯仿 为溶剂， 反应 3.0h， 以85%的产率得到(mesityl)C((C4H2N)(C6H4)O)2B
  参考文献：
  名称：

  Convenient and highly efficient synthesis of boron–dipyrrins bearing an arylboronate center

  摘要：

  Novel boron-dipyrrins bearing an aryl group and a phenyloxy group linked directly to the boron center have been prepared in high yields from arylboronic acid. The unique Coordination geometry around the boron was determined by an X-ray crystallographic analysis. The complexes showed a strong fluorescence, and alkylation of the OH group shifted the emission to a longer wavelength with a larger Stokes shift.

  DOI：

  10.1016/j.tetlet.2009.02.094

文献信息

• Aluminium complexes of N2O2-type dipyrrins: the first hetero-multinuclear complexes of metallo-dipyrrins with high fluorescence quantum yields
  作者：Chusaku Ikeda、Satoko Ueda、Tatsuya Nabeshima

  DOI：10.1039/b820141b

  日期：——

  The aluminium complexes of N2O2-dipyrrins were synthesized and the absorption/fluorescence spectral changes caused by the complex formation with ZnCl2, ZnBr2 and Zn(OAc)2 were examined.

  合成了N2O2-二吡咯金属络合物，并研究了与ZnCl2、ZnBr2和Zn(OAc)2形成络合物所导致的吸收/荧光光谱变化。