2,3,3,3-Tetrafluoro-2-[1,1,2,3,3,3-hexafluoro-2-(1,1,2-trifluoroprop-2-enoxy)propoxy]propanoic acid | 174082-84-9

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 2,3,3,3-Tetrafluoro-2-[1,1,2,3,3,3-hexafluoro-2-(1,1,2-trifluoroprop-2-enoxy)propoxy]propanoic acid
• CAS: 174082-84-9
• 化学式: C₉H₃F₁₃O₄
• 分子量: 422.1
• InChiKey: XZZGVKGGECJBDP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  26
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  55.8
• 氢给体数：
  1
• 氢受体数：
  17

文献信息

• FLUOROOLEFIN, FLUOROPOLYMER, AND THERMOPLASTIC RESIN COMPOSITION CONTAINING THE POLYMER
  申请人：DAIKIN INDUSTRIES, LIMITED

  公开号：EP0728776A1

  公开（公告）日：1996-08-28

  To provide a fluorine-containing olefin represented, for example, by CH2=CFCF2-Rf6-(CH2)k-X2 [wherein, X2 is -CH2OH, Rf6 is a fluorine-substituted fluorine-containing alkyl group having 1 to 40 carbon atoms or -ORf7- (Rf7 is a fluorine-substituted fluorine-containing alkyl group having 1 to 40 carbon atoms or a fluorine-substituted fluorine-containing ether group having 3 to 50 carbon atoms), k is 0 or an integer of 1 to 6]; a fluorine-containing polymer with functional group which is prepared by polymerizing the above-mentioned olefin, has good affinity with various heat-resisting thermoplastic resins and is capable of forming homogeneous dispersion with the thermoplastic resin; and a thermoplastic resin composition comprising the above-mentioned fluorine-containing polymer with functional group and an aromatic polyester or the like as the heat-resisting thermoplastic resin.

  提供一种含氟烯烃，例如由CH2=CFCF2-Rf6-( )k-X2[其中，X2是- OH、 Rf6 是具有 1 至 40 个碳原子的氟取代的含氟烷基或-ORf7-（Rf7 是具有 1 至 40 个碳原子的氟取代的含氟烷基或具有 3 至 50 个碳原子的氟取代的含氟醚基），k 是 0 或 1 至 6 的整数]；通过聚合上述烯烃制备的含氟官能团聚合物，该聚合物与各种耐热热塑性树脂具有良好的亲和性，并能与热塑性树脂形成均匀的分散体；以及由上述含氟官能团聚合物和作为耐热热塑性树脂的芳香族聚酯或类似物组成的热塑性树脂组合物。
• THIN COATING FILM MADE OF FLUOROPOLYMER AND METHOD OF FORMING THE SAME
  申请人：Daikin Industries, Ltd.

  公开号：EP1162244A1

  公开（公告）日：2001-12-12

  To provide the method of forming the thin coating film of fluorine-containing polymer having heat resistance and non-sticking property by adhering directly to a substrate without lowering characteristics such as reflection and light transmission which the substrate has. The thin coating film is a film which comprises a continuous layer of fluorine-containing polymer formed by adhering directly to the substrate and has a thickness of less than 3 µm, wherein the fluorine-containing polymer in the coating film has a hydrophilic functional group and a crystalline melting point of not less than 200°C

  提供一种方法，在不降低基材所具有的反射和透光等特性的情况下，通过直接粘附在基材上形成具有耐热性和不粘性的含氟聚合物薄膜。该薄膜是由直接附着在基材上形成的含氟聚合物连续层组成的薄膜，厚度小于 3 微米，其中涂膜中的含氟聚合物具有亲水官能团，结晶熔点不低于 200°C
• NOVEL FLUOROPOLYMER HAVING ACID-REACTIVE GROUP AND CHEMICAL AMPLIFICATION TYPE PHOTORESIST COMPOSITION CONTAINING THE SAME
  申请人：Daikin Industries, Ltd.

  公开号：EP1275666A1

  公开（公告）日：2003-01-15

  There is provided a novel fluorine-containing polymer having an acid-reactive group which has a high transparency against energy rays (radioactive rays) in a vacuum ultraviolet region (157 nm), and further there are provided a material for fluorine-containing base polymer prepared from the polymer and suitable for a photoresist and a chemically amplifying type resist composition obtained therefrom. The polymer has a number average molecular weight of from 1,000 to 1,000,000 and represented by the formula: -(M1)-(M2)-(A)-, wherein M1 is a structural unit having an acid-labile or acid-degradable functional group, M2 is a structural unit of fluorine-containing acryl ester, A is a structural unit derived from other copolymerizable monomer, the percent by mole ratio M1/M2 is 1 to 99/99 to 1 and the polymer comprises from 1 to 99 % by mole of the structural unit M1, from 1 to 99 % by mole of the structural unit M2 and from 0 to 98 % by mole of the structural unit A1. The material for fluorine-containing base polymer comprises a fluorine-containing polymer having an acid-reactive group such as the above-mentioned polymer and is suitable for a photoresist, and the chemically amplifying type resist composition is obtained from those polymer and material.

  本发明提供了一种具有酸反应基团的新型含氟聚合物，该聚合物对真空紫外线区域（157 纳米）的能量射线（放射性射线）具有高透明度，此外还提供了一种由该聚合物制备的、适用于光刻胶的含氟基础聚合物材料，以及由该聚合物制备的化学放大型抗蚀剂组合物。 该聚合物的平均分子量为 1,000 到 1,000,000 之间，由式表示：-(M1)-(M2)-(A)-，其中 M1 是具有酸性或酸性可降解官能团的结构单元，M2 是含氟丙烯酸酯的结构单元，A 是来自其他可共聚单体的结构单元，M1/M2 的摩尔比为 1 至 99/99 至 1，聚合物包括 1 至 99 %（以摩尔计）的结构单元 M1、1 至 99 %（以摩尔计）的结构单元 M2 和 0 至 98 %（以摩尔计）的结构单元 A1。含氟基聚合物的材料包括具有酸反应基团的含氟聚合物，如上述聚合物，并适用于光刻胶，化学放大型抗蚀剂组合物由这些聚合物和材料获得。
• OPTICAL MATERIAL CONTAINING FUNCTIONAL FLUOROPOLYMER
  申请人：Daikin Industries, Ltd.

  公开号：EP1375589A1

  公开（公告）日：2004-01-02

  There is provided an optical material obtained from an organic composition which is suitable for an optical material in optical communication and comprises a fluorine-containing polymer having functional group and a rare earth metal ion, in which the fluorine-containing polymer having functional group has at least one ketone structure in its side chain and a maximum absorption coefficient of not more than 1 cm-1 in each wavelength range of from 1,290 to 1,320 nm, from 1,530 to 1,570 nm and from 600 to 900 nm and the rare earth metal ion is at least one selected from the group consisting of erbium (Er) ion, thulium (Tm) ion, praseodymium (Pr) ion, holmium (Ho) ion, neodymium (Nd) ion and europium (Eu) ion.

  本发明提供了一种从有机组合物中获得的光学材料，该光学材料适用于光通信中的光学材料，由具有官能团的含氟聚合物和稀土金属离子组成，其中具有官能团的含氟聚合物的侧链中至少有一个酮结构，在1、290 至 1,320 纳米、1,530 至 1,570 纳米和 600 至 900 纳米范围内的最大吸收系数不超过 1 cm-1，而稀土金属离子至少选自由铒 (Er) 离子、铥 (Tm) 离子、镨 (Pr) 离子、钬 (Ho) 离子、钕 (Nd) 离子和铕 (Eu) 离子组成的组中的一种。
• METHOD FOR FORMING MULTILAYER RESIST
  申请人：DAIKIN INDUSTRIES, LTD.

  公开号：EP1686425A1

  公开（公告）日：2006-08-02

  There is formed a laminated resist which exhibits sufficient reflection reducing effect in a photolithography process using light of vacuum ultraviolet region and also has sufficient developing characteristics in a developing process. The method of forming the laminated photoresist comprises (I) a step for forming the photoresist layer (L1) on a substrate and (II) a step for forming the antireflection layer (L2) on the photoresist layer (L1) by applying the coating composition containing the fluorine-containing polymer (A) having hydrophilic group Y. The fluorine-containing polymer (A) contains a structural unit derived from a fluorine-containing ethylenic monomer having hydrophilic group Y and is characterized in that (i) the hydrophilic group Y contains an acidic OH group having a pKa value of not more than 11, (ii) a fluorine content is not less than 50 % by mass, and (iii) the number of moles of the hydrophilic group Y in 100 g of the fluorine-containing polymer (A) is not less than 0.14.

  形成了一种层状光刻胶，它在使用真空紫外区光的光刻工艺中显示出足够的减反射效果，并且在显影工艺中具有足够的显影特性。形成层状光刻胶的方法包括：(I) 在基底上形成光刻胶层 (L1) 的步骤；(II) 在光刻胶层 (L1) 上形成抗反射层 (L2) 的步骤，该步骤通过涂敷含有亲水基团 Y 的含氟聚合物 (A) 的涂层组合物来实现。含氟聚合物(A)含有由具有亲水基团 Y 的含氟乙烯单体衍生的结构单元，其特征在于：(i) 亲水基团 Y 含有 pKa 值不大于 11 的酸性 OH 基团；(ii) 氟含量不小于 50%（按质量计）；(iii) 100 克含氟聚合物(A)中亲水基团 Y 的摩尔数不小于 0.14。