tris(N,N-diethyldithiocarbamato-S,S')phenyltin | 34842-39-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: tris(N,N-diethyldithiocarbamato-S,S')phenyltin
• CAS: 34842-39-2
• 化学式: C₂₁H₃₅N₃S₆Sn
• 分子量: 640.635
• InChiKey: SPRHHUHJJBIMMP-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  sodium N,N-diethyldithiocarbamate 、 苯基三氯化锡 以 甲醇 为溶剂， 生成 tris(N,N-diethyldithiocarbamato-S,S')phenyltin 、 sodium chloride
  参考文献：
  名称：

  Tris(N,N-diethyldithiocarbamato-S,S')phenyltin

  摘要：

  The title structure, [Sn(C5H10NS2)(3)(C6H5)], consists of monomeric molecular chelate complexes in which the Sn atom has distorted pentagonal bipyramidal coordination with five S atoms in equatorial sites. One of the dithiocarbamate ligands has a short [2.570 (2) Angstrom] and a long [2.766 (2) Angstrom] Sn-S distance, a second dithiocarbamate ligand has almost equal Sn-S distances [2.676 (2) and 2.602 (2) Angstrom] and the axial-equatorial dithiocarbamate ligand has a long equatorial Sn-S distance [2.757 (2) Angstrom] and a short axial Sn-S distance [2.458 (2) Angstrom]. The axial Sn-C distance is 2.113 (3) Angstrom. Distortion from the idealized pentagonal bipyramid has been attributed to the steric requirements of the four-membered MS(2)C ring and to the limited bite angle of the dithiocarbamate ligand.

  DOI：

  10.1107/s0108270194004853