1,2-bis(decyloxy)-4,5-dinitrobenzene | 171418-23-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,2-bis(decyloxy)-4,5-dinitrobenzene
• 英文别名: 1,2-Didecoxy-4,5-dinitrobenzene
• CAS: 171418-23-8
• 化学式: C₂₆H₄₄N₂O₆
• 分子量: 480.645
• InChiKey: QKJDZORXGZHCGU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.5
• 重原子数：
  34
• 可旋转键数：
  20
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.77
• 拓扑面积：
  110
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  1,2-bis(decyloxy)-4,5-dinitrobenzene 在 palladium 10% on activated carbon 、 一水合肼 作用下， 以 乙醇 为溶剂， 反应 24.0h， 生成 1,4-dichloro-7,8-bis(decyloxy)phenazine-2,3-diol
  参考文献：
  名称：

  Synthesis, Characterization, and Nonvolatile Ternary Memory Behavior of a Larger Heteroacene with Nine Linearly Fused Rings and Two Different Heteroatoms

  摘要：

  To achieve ultrahigh density memory devices with the capacity of 3(n) or larger, organic materials with multilevel stable states are highly desirable. Here, we reported a novel larger stable heteroacene, 2,3,13,14-tetradecyloxy-5,11,16,22-tetraaza-6,10,17,21-tetrachloro-7,9,18,20-tetraoxa-8,19-dicyanoenneacene (CDPzN), which has two different types of heteroatoms (O and N) and nine linearly fused rings. The sandwich-structure memory devices based on CDPzN exhibited excellent ternary memory behaviors with high ON2/ON1/OFF current ratios of 10(6.3)/10(4.3)/1 and good stability for these three states.

  DOI：

  10.1021/ja408208c
• 作为产物：
  描述：

  1,2-(二十二烷氧荃)苯 在 硫酸 、 硝酸 作用下， 以 二氯甲烷 为溶剂， 反应 16.0h， 生成 1,2-bis(decyloxy)-4,5-dinitrobenzene
  参考文献：
  名称：

  疏溶剂控制的核心取代萘二酰亚胺纳米结构。

  摘要：

  在MeOH-CHCl（3）解决方案中探讨了将2,3-环氧基取代的NDI自组装成离散的蠕虫状纳米结构的要求。AFM用于可视化和表征在精确比例的溶剂混合物中形成的结构。

  DOI：

  10.1039/b920015k

文献信息

• In Situ Synthesis of Hexakis(alkoxy)diquinoxalino[2,3-<i>a</i>:2‘,3‘-<i>c</i>]phenazines:  Mesogenic Phase Transition of the Electron-Deficient Discotic Compounds
  作者：Chi Wi Ong、Su-Chih Liao、Tsu Hsing Chang、Hsiu-Fu Hsu

  DOI：10.1021/jo035840l

  日期：2004.4.1

  2,3,8,9,14,15-Hexakis(alkoxy)diquinoxalino[2,3-a:2‘,3‘-c]phenazines with alkyl side chains varying from 6 to 12 carbon atoms were readily synthesized by the condensation of hexaketocyclohexane with the respective 1,2-bisalkoxy-4,5-diaminobenzene. Polarization microscopy and DSC studies showed all these compounds to exhibit a very wide mesophase range of over 150 °C. An interesting Dhd to Drd transition

  通过缩合反应很容易合成2,3,8,9,14,15-烷基侧链为6至12个碳原子的六（烷氧基）二喹喔啉[2,3- a：2'，3'- c ]吩嗪六酮环己烷与各自的1，2-双烷氧基-4，5-二氨基苯。偏振显微镜和DSC研究表明，所有这些化合物的中间相范围都超过150°C。通过X射线衍射测量确定，辛基衍生物3b观察到有趣的D hd到D rd跃迁。己基衍生物显示出三个还原电位，这表明HATN核保持了其电子不足的特性，并被认为适合作为n掺杂的盘状液晶材料。六个烷氧基链的合并并没有覆盖HATN核心的电子缺乏。
• Regioselective synthesis of the 4,5-dialkoxy-2-nitroanilines bearing two different alkoxy substituents
  作者：Jarosław Grolik、Paweł Ręka、Magdalena Gorczyca、Katarzyna Stadnicka

  DOI：10.1016/j.tetlet.2022.153830

  日期：2022.6

  chemoselective synthesis of 4,5-dialkoxy-2-nitroanilines substituted with two alkoxys at C-4 and C-5. Here we show the optimization protocol of the transetherification reaction used to synthesize 20 new compounds with good to excellent yields (50–92%). We describe a simple and efficient one-step procedure that can be applied to obtain a significant number of pharmacologically active compounds, including

  本文报道了在 C-4 和 C-5 上被两个烷氧基取代的 4,5-二烷氧基-2-硝基苯胺的区域选择性和化学选择性合成。在这里，我们展示了用于合成 20 种具有良好至优异产率 (50–92%) 的新化合物的醚交换反应的优化方案。我们描述了一种简单而有效的一步程序，可用于获得大量药理活性化合物，包括抗疟药伯氨喹类似物。
• Synthesis and Characterization of a Discotic Uranium-Containing Liquid Crystal
  作者：Jonathan L. Sessler、Wyeth B. Callaway、Stephen P. Dudek、Richard W. Date、Duncan W. Bruce

  DOI：10.1021/ic0492690

  日期：2004.10.1

  chains is described. These compounds are found to be liquid-crystalline and form columnar mesophases, as judged from polarizing optical microscopy studies, and represent the first uranium-containing discotic mesogens.

  描述了几种用脂肪族链官能化的UO（2）-alaskaphyrin衍生物的合成。根据偏振光学显微镜研究判断，发现这些化合物为液晶并形成柱状中间相，代表了首批含铀的盘状介晶。
• Liquid crystalline derivatives for electronic devices
  申请人：UNIVERSITE LIBRE DE BRUXELLES

  公开号：EP1365002A1

  公开（公告）日：2003-11-26

  The present invention is related to a device comprising a liquid crystalline poly-aza-trinaphthylene derivatives of the structure I: wherein A is C-R or N (nitrogen), and B is R1 R is hydrogen (H) or deuterium (D)    halogen (F, Cl, Br or I)    nitro (NO2)    nitryl (CN) R1 is ether (O-R2)    ester (O-CO- R2 or CO-O- R2)    alkyl (R2)    alkyne (C C- R2)    phenyl (mono, di or tri substituted by above-mentioned R2 groups) with R2 being an alkyl, branched or not, an oligoether, or a combination of both, of 5 to 20 carbon atoms.

  本发明涉及一种包含结构 I 的液晶聚氮杂三萘烷衍生物的装置： 其中 A 是 C-R 或 N（氮），B 是 R1 R是氢（H）或氘（D） 卤素（F、Cl、Br 或 I） 硝基（NO2） 硝基（CN） R1 是醚（O-R2） 酯（O-CO- R2 或 CO-O- R2） 烷基 (R2) 炔（C C- R2） 苯基（被上述 R2 基团取代的单、双或三苯基） R2为 5 至 20 个碳原子的烷基（无论是否支链）、低聚醚或两者的组合。
• Effect of Phthalimide in 2,1,3-Benzooxadiazole Based Copolymer on the Performances of Solar Cells
  作者：Thu Trang Do、Ye Eun Ha、Byung-Hyun Ahn、Gun Dae Lee、Joo Hyun Kim

  DOI：10.1080/15421406.2014.933383

  日期：2014.7.24

  Two newly designed donor-acceptor (D-A) conjugated polymers were prepared from the Stille coupling reactions by incorporating phthalimide derivative as a co-acceptor unit into 2,1,3-benzooxadiazole (BO) and thiophene with different ratios of 5mol.% and 10mol.% of TBO-I 5, TBO-I 10, respectively. Polymers possess moderate molecular weights and excellent thermal properties with a 5% weight loss temperatures (T-d) around 300 degrees C. Compared to poly5,6-bis(decyloxy)-4-(thiophen-2-yl)benzo[c][1,2,5]oxadiazole} (TBO), adding phthalimide unit in TBO-I 5 and TBO-I 10 shifted UV-Vis absorption spectra and changed the HOMO and LUMO levels of polymers. Bulk hetero junction (BHJ) polymer solar cells (PSCs) based on polymers blended with [6,6]-phenyl-C61-butyric acid methyl ester (PC61BM) were fabricated to investigate photovoltaic properties. As a results, with increasing the composition of phthalimide, the J(sc) of the devices based on polymers were reduced in the order of TBO (4.74mA/cm(2)) > TBO-I 5 (3.94mA/cm(2)) > TBO-I 10 (1.90mA/cm(2)) due to the blue-shifted in absorption spectra and twisting in polymer main chain of TBO-I polymers. The decrease in J(sc) led to low photovoltaic performances and the device based on TBO showed higher performances than those of TBO-I 5 and TBO-I 10 with the PCE of 1.66%, the J(sc) of 4.74mA/cm(2), the V-oc of 0.82V and the FF of 42.4% under the illumination of AM 1.5G, 100 mW/cm(2).