cyclopenta-1,3-diene;iron(2+);tributyl-[(5-chlorocyclopenta-1,3-dien-1-yl)methyl]azanium;iodide | 366796-10-3

• 分子结构分类: 有机化合物 - 碳氢化合物 - 芳香烃
• 英文名称: cyclopenta-1,3-diene;iron(2+);tributyl-[(5-chlorocyclopenta-1,3-dien-1-yl)methyl]azanium;iodide
• CAS: 366796-10-3
• 化学式: C₂₃H₃₇ClFeN*I
• 分子量: 545.758
• InChiKey: BZEJISBFKGXNEN-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2-chloro-1-trimethylammoniomethylferrocene iodide 、 三正丁胺 以 乙腈 为溶剂， 生成 cyclopenta-1,3-diene;iron(2+);tributyl-[(5-chlorocyclopenta-1,3-dien-1-yl)methyl]azanium;iodide
  参考文献：
  名称：

  摘要：

  Trialkyl (ferrocenyl methyl)ammonium salts and their 2-substituted analogs designed for the preparation of molecular ferromagnetics based on bimetallic oxalates were synthesized using classical alkylation of dialkylaminomethylferrocenes by alkyl halides and nucleophilic substitution reaction of 2-substituted dimethylaminomethylferrocene methiodides with trialkylamines. In the case of salts with electron-donating substituents in position 2, only the latter of the two proposed routes is applicable because IV-alkylation with alkyl halides is accompanied by competing ferrocenylmethylation of the starting amine. On the contrary, the salts with electron-withdrawing 2-substituents should be prepared preferably by the reaction of amines with alkyl halides, while nucleophilic trialkylamination of methiodides is complicated by deprotonation. induced by bases.

  DOI：

  10.1023/a:1011377611293