zinc 5,10,15,20-tetraphenyl(3'-tetrabromo)porphyrine pyridine | 57304-84-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: zinc 5,10,15,20-tetraphenyl(3'-tetrabromo)porphyrine pyridine
• CAS: 57304-84-4
• 化学式: C₄₉H₂₉Br₄N₅Zn
• 分子量: 1072.81
• InChiKey: ICTKOPCTHFEKTA-YKKPBKTHSA-N

反应信息

• 作为产物：
  描述：

  吡啶 、 meso-5,10,15,20-tetrakis(3-bromophenyl)zinc porphyrin 以 甲苯 为溶剂， 生成 zinc 5,10,15,20-tetraphenyl(3'-tetrabromo)porphyrine pyridine
  参考文献：
  名称：

  摘要：

  Extra coordination of zinc complexes of bromo-substituted tetraphenylporphyrins was studied by spectrophotometry. It was found that the stability of complexes thus formed markedly increases upon beta-bromo-substitution in tetraphenylporphine. The effects of electronic and structural factors on the extra coordination were discussed. The stability constants of complexes formed by zinc porphyrins with organic bases were calculated, and the electronic absorption spectra of porphyrins in toluene and in other organic solvents were studied.

  DOI：

  10.1023/a:1020030714257