9-phenylthioxanthene 10,10-dioxide | 26430-89-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻喃类
• 英文名称: 9-phenylthioxanthene 10,10-dioxide
• 英文别名: 9-phenyl-thioxanthene-10,10-dioxide；9-Phenyl-thioxanthen-10,10-dioxid；9-Phenyl-thioxanthen-SS-dioxid；9-phenyl-9H-thioxanthene 10,10-dioxide
• CAS: 26430-89-7
• 化学式: C₁₉H₁₄O₂S
• 分子量: 306.385
• InChiKey: LABCEXHTIMPNBZ-UHFFFAOYSA-N

物化性质

• 熔点：
  197-199 °C
• 沸点：
  465.4±35.0 °C(Predicted)
• 密度：
  1.293±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  22
• 可旋转键数：
  1
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  42.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2-(苯硫基)苯甲醛 在 硫酸 、 间氯过氧苯甲酸 作用下， 以 乙醚 、 二氯甲烷 、 水 为溶剂， 反应 1.67h， 生成 9-phenylthioxanthene 10,10-dioxide
  参考文献：
  名称：

  Ohno, Sachio; Shimizu, Hiroshi; Kataoka, Tadashi, Chemical and pharmaceutical bulletin, 1984, vol. 32, # 9, p. 3471 - 3482

  摘要：

  DOI：

文献信息

• Gomberg; Britton, Journal of the American Chemical Society, 1921, vol. 43, p. 1947
  作者：Gomberg、Britton

  DOI：——

  日期：——
• OHNO, SACHIO;SHIMIZU, HIROSHI;KATAOKA, TADASHI;HORI, MIKIO, CHEM. AND PHARM. BULL., 1984, 32, N 9, 3471-3482
  作者：OHNO, SACHIO、SHIMIZU, HIROSHI、KATAOKA, TADASHI、HORI, MIKIO

  DOI：——

  日期：——
• LIGHT EMITTING MATERIAL, MANUFACTURE METHOD THEREOF AND ORGANIC LIGHT EMITTING DIODE USING THE LIGHT EMITTING MATERIAL
  申请人：Shenzhen China Star Optoelectronics Technology Co., Ltd.

  公开号：US20180170894A1

  公开（公告）日：2018-06-21

  The present invention provides a light emitting material, a manufacture method thereof and an organic light emitting diode using the light emitting material. The structure is unitary, and the formula weight is determined, and the better solubility and film formation are provided, and the thin film status is stable; it possesses a very high decomposition temperature and a lower sublimation temperature, and is easy to sublime to be light emitting material of high purity, and can be applied for small molecule organic light emitting diode. In the manufacture method of the light emitting material according to the present invention, p-bromophenol and 4-Bromo-2-fluorobenzonitrile are employed to be starting materials, and the intermediate of the light emitting material is obtained with a series of simple reactions, and finally, the light emitting material is obtained with Ullmann reaction or Suzuki reaction, and the steps are simple and the production is high.